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Highly uniform and well-dispersed CeO(2) and CeO(2):Eu(3+) (Sm(3+), Tb(3+)) nanocrystals were prepared by a nonhydrolytic solution route and characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectra (XPS), UV/vis absorption, and photoluminescence (PL) spectra, respectively. The result of XRD indicates that the CeO(2) nanocrystals are well crystallized with a cubic structure. The TEM images illustrate that the average size of CeO(2) nanocrystals is about 3.5 nm in diameter. The absorption spectrum of CeO(2):Eu(3+) nanocrystals exhibits red-shifting with respect to that of the undoped CeO(2) nanocrystals. Under the excitation of 440 nm (or 426 nm) light, the colloidal solution of the undoped CeO(2) nanocrystals shows a very weak emission band with a maximum at 501 nm, which is remarkably enhanced by doping additional lanthanide ions (Eu(3+), Tb(3+), Sm(3+)) in the CeO(2) nanocrystals. The emission band is not due to the characteristic emission of the lanthanide ions but might arise from the oxygen vacancy which is introduced in the fluorite lattice of the CeO(2)nanocrystals to compensate the effective negative charge associated with the trivalent ions.
Indium hydroxide, In(OH)3, nano-microstructures with two kinds of morphology, nanorod bundles (around 500 nm in length and 200 nm in diameter) and caddice spherelike agglomerates (around 750-1000 nm in diameter), were successfully prepared by the cetyltrimethylammonium bromide (CTAB)/water/cyclohexane/n-pentanol microemulsion-mediated hydrothermal process. Calcination of the In(OH)3 crystals with different morphologies (nanorod bundles and spheres) at 600 degrees C in air yielded In2O3 crystals with the same morphology. X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and photoluminescence (PL) spectra as well as kinetic decays were used to characterize the samples. The pH values of microemulsion play an important role in the morphological control of the as-formed In(OH)3 nano-microstructures from the hydrothermal process. The formation mechanisms for the In(OH)3 nano-microstructures have been proposed on an aggregation mechanism. In2O3 nanorod bundles and spheres show a similar blue emission peaking around 416 and 439 nm under the 383-nm UV excitation, which is mainly attributed to the oxygen vacancies in the In2O3 nano-microstructures.
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