In order to improve the corrosion resistance of zinc-rich epoxy coatings and reduce the amount of zinc used, first, graphene oxide (GO) was modified by sulfonated multiwall carbon nanotubes (SMWCNTs) to obtain the modified graphene oxide (SM-GO). The samples were characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD) and Raman spectroscopy. Then, four kinds of coatings were prepared, namely pure zinc-rich coating (0-ZRC), graphene oxide-based zinc-rich coating (GO-ZRC), sulfonated multiwall carbon nanotube-based zinc-rich coating (SM-ZRC) and SM-GO-based zinc-rich coating (SG-ZRC). The corrosion resistance of the above coatings was studied by open circuit potential (OCP), electrochemical impedance spectroscopy (EIS), a salt spray test, 3D confocal microscope, and electron scanning electron microscope (SEM). The results indicate that GO is successfully non-covalently modified by SMWCNTs, of which the interlayer spacing increases and dispersion is improved. The order of the corrosion resistance is GO-ZRC > SG-ZRC > SM-ZRC > 0-ZRC. The addition of GO, SMWCNTs, and SM-GO increases the shielding effect and increases the electrical connection between Zn particles and metal substrates, which improves the corrosion resistance. However, SMWCNTs and SM-GO also strengthen the galvanic corrosion, which decreases the corrosion resistance to some extent.

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The study of rock damage evolution is of great significance in the field of underground engineering. In this paper, the damage development of deep formation rock was quantitatively evaluated by acoustic emission (AE) test. The Young’s modulus of the test rock specimens under ideal intact state was obtained by assuming a linear relationship between the AE rate parameter and the damage variation based on the rate process theory. Through the multi-stage cyclic loading test, the damage parameters corresponding to the peak stress of the previous stage were calculated by using the tangent modulus at the initial moment. The results showed that there was abrupt transition stage of damage development with the linear increase of stress. The damage parameter curves of rock specimens during loading process were obtained by using the method of cumulative AE energy, and the development trend of the curves was analyzed simply by combining the concepts of crack initiation stress and crack damage stress. Comparing the two methods of obtaining damage parameters by using cyclic loading test and cumulative AE energy, the results of them were highly consistent except for some deviation in the initial and final stages.