In this paper, we analyzed interannual variations of normalized difference vegetation index (NDVI) and their relationships with climatic variables (temperature and precipitation) and human activity in China between 1982 and 1999. Monthly and seasonal NDVI increased significantly at both the country and biome scales over the study period. NDVI shows the largest increase (14.4% during the 18 years and a trend of 0.0018 yr−1) over 85.9% of the total study area in spring and the smallest increase (5.2% with a trend of 0.0012 yr−1) over 72.2% of the area in summer. The NDVI trends show a marked heterogeneity corresponding to regional and seasonal variations in climates. There is about a 3‐month lag for the period between the maximum trend in temperature (February) and that in NDVI (April or May) at the country and biome scales. Human activity (urbanization and agricultural practices) also played an important role in influencing the NDVI trends over some regions. Rapid urbanization resulted in a sharp decrease in NDVI in the Yangtze River and Pearl River deltas, while irrigation and fertilization may have contributed to the increased NDVI in the North China plain.

SUMMARYThe unbiased and comprehensive analysis of metabolites in any organism presents a major challenge if proper peak annotation and unambiguous assignment of the biological origin of the peaks are required. Here we provide a comprehensive multi-isotope labelling-based strategy using fully labelled 13 C, 15 N and 34 S plant tissues, in combination with a fractionated metabolite extraction protocol. The extraction procedure allows for the simultaneous extraction of polar, semi-polar and hydrophobic metabolites, as well as for the extraction of proteins and starch. After labelling and extraction, the metabolites and lipids were analysed using a highresolution mass spectrometer providing accurate MS and all-ion fragmentation data, providing an unambiguous readout for every detectable isotope-labelled peak. The isotope labelling assisted peak annotation process employed can be applied in either an automated database-dependent or a database-independent analysis of the plant polar metabolome and lipidome. As a proof of concept, the developed methods and technologies were applied and validated using Arabidopsis thaliana leaf and root extracts. Along with a large repository of assigned elemental compositions, which is provided, we show, using selected examples, the accuracy and reliability of the developed workflow.

Previous modeling and empirical studies have shown that the biophysical impact of deforestation is to warm the tropics and cool the extratropics. In this study, we use an earth system model of intermediate complexity to investigate how deforestation on various spatial scales affects ground temperature, with an emphasis on the latitudinal temperature response and its underlying mechanisms. Results show that the latitudinal pattern of temperature response depends nonlinearly on the spatial extent of deforestation and the fraction of vegetation change. Compared with regional deforestation, temperature change in global deforestation is greatly amplified in temperate and boreal regions but is dampened in tropical regions. Incremental forest removal leads to increasingly larger cooling in temperate and boreal regions, while the temperature increase saturates in tropical regions. The latitudinal and spatial patterns of the temperature response are driven by two processes with competing temperature effects: decrease in absorbed shortwave radiation due to increased albedo and decrease in evapotranspiration. These changes in the surface energy balance reflect the importance of the background climate in modifying the deforestation impact. Shortwave radiation and precipitation have an intrinsic geographical distribution that constrains the effects of biophysical changes and therefore leads to temperature changes that are spatially varying. For example, wet (dry) climate favors larger (smaller) evapotranspiration change; thus, warming (cooling) is more likely to occur. Our analysis reveals that the latitudinal temperature change largely results from the climate conditions in which deforestation occurs and is less influenced by the magnitude of individual biophysical changes such as albedo, roughness, and evapotranspiration efficiency.Published by Copernicus Publications on behalf of the European Geosciences Union.

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The high-active sorbent for SO2 removal was developed by mixing CaO particles with fly ash in water at ambient temperature. The calcium utilization rate in the sorbent was achieved to 60% after the desulfurization reaction at 450 °C for 90 min, while the utilization rate for original pure CaO particles was only 21% under the identical conditions. The surface of the sorbent was examined by SEM, EDX, and BET analysis to study the activation mechanism. Results indicated that CaO particles were separated to several small particles of Ca(OH)2 in water due to a significant heat release, while a small amount of Ca(OH)2 dissolved in water. Under the condition of coexistence with fly ash particles, the tiny Ca(OH)2 particles and its solute covered the surface of fly ash particles with the drying process. Therefore, SO2 could react efficiently with the Ca(OH)2 on the surface of fly ash particles. XRD analysis showed that the composition of sorbent was not apparently changed in the sorbent preparation process. Moreover, the mixture time of CaO and fly ash in water did not play a significant role on calcium utilization rate. These results revealed that the hydration reactions between CaO and the materials such as SiO2 or Al2O3 in fly ash were limited in sorbent preparation process at ambient temperature. The IR analysis of reaction products indicated that gypsum could be produced efficiently at high reaction temperature by using the sorbent.