This work summarizes the main results of the operation of the International Program "Luminescence of Cave Minerals" of the commission on Physical Chemistry and Hydrogeology of Karst of UIS of UNESCO in the field of activators of speleothem luminescence. It discusses Activators of Luminescence in Speleothems as a source of major mistakes in the interpretation of luminescent paleoclimatic records. It demonstrates the existence of 6 types of luminescence of speleothems and cave minerals in dependence of the type of the luminescence center and its incorporation in the mineral. 24 different activators of photoluminescence of speleothem calcite and 11 of aragonite are studied. This paper demonstrates that it is impossible to produce reliable Paleotemperature or Past Precipitation records from luminescence of speleothems without establishing the organic origin of the entire luminescence of the particular sample.
We observed cycles presented in a luminescent solar insolation proxy record from a speleothem from Jewel Cave, South Dakota, US. We found cycles of orbital precession with periods of 23 and 19 ka and of obliquity of 41 ka and many others from non-orbital origin in this sample. We determined the Solar origin of the cycles with durations of 11500, 4400, 3950, 2770, 2500, 2090, 1960, 1670, 1460, 1280, 1195, 1145, 1034, 935, 835, 750 and 610 years. It was done by their detection both in proxy records of speleothem luminescence, ∆ 14 C and the intensity of the geomagnetic dipole. It is well known that the main variations in the last two records are produced by the solar wind. The most intensive cycle discovered in this record has duration of 11.5 ka. It is not of orbital origin. It was found previously to be the most intensive cycle in the ∆ 14 C calibration record and has been interpreted to be of terrestrial origin because "it is too strong to be of solar origin". Our studies suggest that it should be a solar cycle modulating the geomagnetic field and 14 C reversed production as the other solar cycles do.
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