Uniform NiS2 nanocubes are successfully synthesized with a microwave-assisted method. Interestingly, NiS2 nanocubes, nanospheres and nanoparticles are obtained by controlling microwave reaction time. NiS2 nanomaterials are primarily applied to supercapacitors and cocatalytic enhancing photocatalytic H2 production. Different morphologies of NiS2 nanostructures show different electrochemical and cocatalytic enhancing H2 production activities. Benefited novel nanostructures, NiS2 nanocube electrodes show a large specific capacitance (695 F g−1 at 1.25 A g−1) and excellent cycling performance (the retention 93.4% of initial specific capacitance after 3000 cycles). More importantly, NiS2 nanospheres show highly cocatalytic enhancing photocatalytic for H2 evolution, in which the photocatalytic H2 production is up to 3400 μmol during 12 hours under irradiation of visible light (λ>420 nm) with an average H2 production rate of 283 μmol h−1.
Copper (Cu) superstructures have been originally synthesized by using natural sapless leaves. A novel hybrid nanoarchitecture, Cu-MnO 2 composite, is prepared through facile coating of a thin MnO 2 nanofilm onto the highly electronically conductive Cu superstructures. Benefiting from their unique structures, as electrode materials of supercapacitors the composite superstructures have a high specific capacity of 1024 F g À1 at 1.5 A g À1 and good capacity retention of around 96% after 2000 electrochemical cycles.
Three-dimensional graphene-based nanocomposites for high energy density Li-ion batteries are summarized comprehensively including the challenges, recent progresses, and perspectives.
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