A simple and efficient approach to orange II (AOII) degradation using Co 2+ −HCO 3 − system as the catalyst and H 2 O 2 as the oxidant under mild reaction conditions was reported. Complete decolorization of 50 μM AOII was observed with 5 μM Co 2+ ions and 4 mM H 2 O 2 in 10 mM NaHCO 3 aqueous solution after 10 min, which was much faster that that of Fenton reagent with 50 μM Fe 2+ ions. Some intermediate products such as carboxylic acids were detected by electrospray ionization-ion trap mass spectrometry and ion chromatography. In the presence of other pollutants such as methylene blue, sulforhodamine B, and a significant amount of anions including Cl, and CH 3 COO − , AOII was still rapidly degraded. The results of photoluminescence probing technology, electron spin resonance spin-trapping technology, and radical trap experiments indicated that the tightly associated hydroxyl radicals with the cobalt complex were the reactive species for AOII degradation.
This paper designs and analyzes the hybrid flexure hinge composed of half a hyperbolic flexure hinge and half a corner-filleted flexure hinge. As it is transversely asymmetric, it has different performance when the fixed and free ends switch. Considering the diversion of rotation center from midpoint, closed-form equations are formulated to characterize both the active rotation and all other in-plane parasitic motion by the Castigliano's second theorem. The maximum stress is evaluated as well. These equations are verified by the finite element analysis and experimentation. The compliance precision ratios are proposed to indicate flexure hinges' ability of preserving the rotation center when they have the same displacement at the free end. The hybrid flexure hinges are compared with five kinds of common notch flexure hinges (circular, corner-filleted, elliptical, hyperbolic, and parabolic flexure hinges) quantitatively based on compliance, precision, compliance precision ratios, and the maximum stress. Conclusions are drawn regarding the performance of these six kinds of flexure hinges.
In order to achieve efficient CO2 capture, four novel microporous organic polymers, based on distinct polycyclic aromatic hydrocarbons, were successfully prepared by the solvent knitting method.
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