Developing a general, facile, and direct strategy for synthesizing thin films of covalent organic frameworks (COFs) is a major challenge in this field. Herein, we report an unprecedented electrocleavage synthesis strategy to produce imine-linked COF films directly on electrodes from electrolyte solutions at room temperature. This strategy enables the cathodic exfoliation of the COF powders to nanosheets by electrochemical reduction and protonation, followed by nanosheets migrating to the anode and reproducing the COF structures by anodic oxidation. Our method is adaptable with most imine-linked COFs by virtue of the low redox potential of the imine bonds, whereas the COF films possess high crystallinity and hierarchical porosity. We highlight these COF films as a superb platform for promoting mass transfer by demonstrating their extraordinarily rapid iodine adsorption with record-high rate constants.
Some hydrocarbon reservoirs are trapped beneath salt bodies, where seismic imaging is greatly challenged due to poor illumination. Multiple reflections have different propagation wave paths from primary reflections and thus can be used to complement the illuminations where primary reflections from beneath the salt are not acquired. Consequently, migration of multiples can sometimes provide better subsalt images compared to conventional migration which uses primary reflections only. In this paper, we propose to modify conventional reverse time migration so that multiples can be used as constructive reflection energy for subsalt imaging. This new approach replaces the impulsive source wavelet with the recorded data containing both primaries and multiples and uses predicted multiples as the input data instead of primary reflections. In the reverse time migration process, multiples recorded on the surface are extrapolated backward in time to each depth level, and the observed data with both primaries and multiples are extrapolated forward in time to the same depth levels, followed by a crosscorrelation imaging condition. A numerical test on the Sigsbee2B data set shows that a wider coverage and a more balanced illumination of the subsurface can be achieved by migration of multiples compared with conventional migration of primary reflections. This example demonstrates that reverse time migration of multiples might be a promising method for complex subsalt imaging.
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