It has been a long-standing challenge to produce air-stable few- or monolayer samples of phosphorene because thin phosphorene films degrade rapidly in ambient conditions. Here we demonstrate a new highly controllable method for fabricating high quality, air-stable phosphorene films with a designated number of layers ranging from a few down to monolayer. Our approach involves the use of oxygen plasma dry etching to thin down thick-exfoliated phosphorene flakes, layer by layer with atomic precision. Moreover, in a stabilized phosphorene monolayer, we were able to precisely engineer defects for the first time, which led to efficient emission of photons at new frequencies in the near infrared at room temperature. In addition, we demonstrate the use of an electrostatic gate to tune the photon emission from the defects in a monolayer phosphorene. This could lead to new electronic and optoelectronic devices, such as electrically tunable, broadband near infrared lighting devices operating at room temperature.

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The development of thermokarst lakes in permafrost regions can relate to climate change and significantly impact the hydrological regime. We investigated the configuration of permafrost and a talik under a thermokarst lake on the Qinghai–Tibet Plateau (QTP), China, using GPR, electrical resistivity tomography, drilling and ground temperature measurements. The boundaries and ice content of permafrost and the talik were identified adjacent to and under the lake. The thickness of permafrost differed by about 4 m on opposite sides of the lake. The thickness and extent of ice‐rich permafrost under the northwest shore was greater than under the southeast shore. A talik penetrated the permafrost base beneath both the shallower and deeper parts of the lake, where water depths were all less than the maximum thickness of winter ice. The talik was wider beneath shallower parts of the lake than in deeper areas. This investigation demonstrates that a through‐talik developed although the water depth was less than the maximum thickness of winter ice, indicating that the general relation between water depth and ice thickness is not reliable for identifying the nature of taliks on the QTP. Copyright © 2017 John Wiley & Sons, Ltd.

Land use and cover changes (LUCC) in permafrost regions have significant consequences on ecology, engineered systems, and the environment. Obtaining more details about LUCC is crucial for sustainable development, land conservation, and environment management. The Hola Basin (957 km2) in the northernmost part of Northeast China, a boreal forest landscape underlain by discontinuous, sporadic, and isolated permafrost, was selected for the case study. The LUCC was analyzed using the Landsat archive of satellite images from 1973 to 2019. A thematic change detection analysis was performed by combining the object-based image analysis (OBIA) and the Support Vector Machine (SVM) algorithm. Four types of LUCC (forest, grass, water, and anthropic) were extracted with an overall accuracy of 80% for 1973 and >90% for 1986, 2000, and 2019. Forest, the dominant class (750 km2 in 1973), declined by 88 km2 (11.8%) from 1973 to 1986 but had a recovery of 78 km2 (12.5%) from 2000 to 2019. Grass, the second-largest class (187 km2 in 1973), increased by 86 km2 (46.5%) between 1973 and 1986 and decreased by 90 km2 (40%) between 2000 and 2019. The anthropic class continuously increased from 10 km2 (1973) to 37 km2 (2019). Major features in LUCC are attributed to rapid population growth, resource exploitation, agriculture intensification, economic development, and frequent forest fires. Under a pronounced climate warming, these drivers have been accelerating the degradation of permafrost, subsequently triggering natural hazards and deteriorating the ecological environment. This study represents a benchmark for sustainable LUCC management in the Hola Basin, Northeast China.