Nickel hexacyanoferrate (NiHCF) film was prepared and characterized on gold and thiol self-assembled monolayers (SAMs)-modified gold electrodes. It was found that the film exhibited some different electrochemical characteristics compared with that found on a carbon electrode. In the presence of K + , the film exhibited a redox peak at about 0.5 V. The peak potential shifted linearly with the K + concentration over the range of about 0.1 mM -0.1 M with slopes of 54 -60 mV per log[K + ]. However, in solutions containing Na + , Li + or NH4 + ion the film did not generate well-defined peaks, or even a visible redox peak. Therefore, the film showed a selective potential response to K + . The voltammetric behavior of NiHCF film varied with thiols, the preparation procedure and the solution pH. Under certain conditions, the characteristics of the film could be improved to some extent.
Posted facial expressions on social networks have been used as a gauge to assess the emotional perceptions of urban forest visitors. This approach may be limited by the randomness of visitor numbers and park locations, which may not be accounted for by the range of data in local tree inventories. Spatial interpolation can be used to predict stand characteristics and detect their relationship with posted facial expressions. Shaoguan was used as the study area where a tree inventory was used to extract data from 74 forest stands (each sized 30 m × 20 m), in which the range was increased by interpolating the stand characteristics of another 12 urban forest parks. Visitors smiled more in parks in regions with a high population or a large built-up area, where trees had strong trunks and dense canopies. People who displayed sad faces were more likely to visit parks located in regions of hilly mountains or farmlands, where soils had a greater total nitrogen concentration and organic matter. Our study illustrates a successful case in using data from a local tree inventory to predict stand characteristics of forest parks that attracted frequent visits.
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