Directed self-assembly (DSA) of block copolymers (BCPs) combines advantages of conventional photolithography and polymeric materials and shows competence in semiconductors and data storage applications. Driven by the more integrated, much smaller and higher performance of the electronics, however, the industry standard polystyrene-block-poly(methyl methacrylate) (PS-b-PMMA) in DSA strategy cannot meet the rapid development of lithography technology because its intrinsic limited Flory-Huggins interaction parameter (χ). Despite hundreds of block copolymers have been developed, these BCPs systems are usually subject to a trade-off between high χ and thermal treatment, resulting in incompatibility with the current nanomanufacturing fab processes. Here we discover that polystyrene-b-poly(propylene carbonate) (PS-b-PPC) is well qualified to fill key positions on DSA strategy for the next-generation lithography. The estimated χ-value for PS-b-PPC is 0.079, that is, two times greater than PS-b-PMMA (χ = 0.029 at 150 °C), while processing the ability to form perpendicular sub-10 nm morphologies (cylinder and lamellae) via the industry preferred thermal-treatment. DSA of lamellae forming PS-b-PPC on chemoepitaxial density multiplication demonstrates successful sub-10 nm long-range order features on large-area patterning for nanofabrication. Pattern transfer to the silicon substrate through industrial sequential infiltration synthesis is also implemented successfully. Compared with the previously reported methods to orientation control BCPs with high χ-value (including solvent annealing, neutral top-coats, and chemical modification), the easy preparation, high χ value, and etch selectivity while enduring thermal treatment demonstrates PS-b-PPC as a rare and valuable candidate for advancing the field of nanolithography.
Mechanical properties of methane hydratebearing-sediments (MHBS) are basic parameters for safety analysis of hydrate exploration and exploitation. Young's modulus, cohesion, and internal friction angle of hydratebearing sediments synthesized in laboratory, are investigated using tri-axial tests. Stress-strain curves and strength parameters are obtained and discussed for different compositions and different hydrate saturation, followed by empirical expressions related to the cohesion, internal friction angle, and modulus of MHBS. Almost all tested MHBS samples exhibit plastic failure. With the increase of total saturation of ice and methane hydrate (MH), the specimens' internal friction angle decreases while the cohesion increases.
Understanding methane adsorption behavior on deep shales is crucial for estimating the original gas in place and enhancing gas recovery in deep shale gas formations. In this study, the methane adsorption on deep shales within the lower Silurian Longmaxi formation from the Sichuan Basin, South China was conducted at pressures up to 50 MPa. The effects of total organic carbon (TOC), temperatures, clay minerals, and moisture content on the adsorption capacity were discussed. The results indicated that the methane excess adsorption on deep shales increased, then reached its peak, and finally decreased with the pressure. The excess adsorption data were fitted using the adsorption models, and it was found that the Dubinin–Radushkevich (D–R) model was superior to other models in predicting the methane adsorption behavior. The methane adsorption capacities exhibited strong positive correlations with the TOC content and negative relationships with clay minerals. The methane excess adsorption decreased with the temperature, while the opposite trend would occur once it exceeded some pressure. The presence of the moisture content on deep shales sharply decreased the methane adsorption capacities, and the reduction of the adsorption capacity decreased with the pressure. The moisture would occupy the adsorption sites in the shale pores, which could result in the methane adsorption capacity that decreased.
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