Clioquinol
(CQ) is a mass-produced drug with broad-spectrum antifungal
and antibacterial properties. This neurodegenerative medicine has
attracted significant attention in the pharmaceutical field. However,
excessive administration of CQ presents neurotoxic effects that require
its early detection and effective countermeasures. Electrochemical
detection can be beneficial in this regard, using functional material
architectures with multiple advanced features. A unique emphasis is
placed on manipulating these hierarchical structures, for advanced
functions, offering an impressive perspective for monitoring systems.
In this paper, we report on the innovative synthesis of distinct structures
of AB2O4 (AB = Zn, Co, and Mn) spinel metal
oxide anchored sulfur-doped reduced graphene oxide (S-rGO) for the
effective detection of CQ. Fascinatingly, unique flower-like manganese
cobaltite (MCO) exhibits superior structural advantages over other
spinels, and doping of S-rGO into the framework marks a significant
improvement in electrochemical properties. The highly symmetrical
floral architecture with straight edges and facets provides defect-rich
active sites, and the dissolution of S-rGO facilitates faster electron
transfer and improved surface area. A wide linear response range,
low detection limit, excellent reproducibility, and stability show
that this material offers an efficient electrocatalyst that reinforces
the practical viability of S-rGO doped MCO spinel for analysis and
monitoring of real samples. The unique structural characteristics
of the synthesized electrocatalyst can further extend its functions
and applications, thereby expanding its potential capabilities.
In
this work, uniform hierarchical mesoporous 3D-urchin-like Bi2S3@2D-nanosheet g-C3N4 was
synthesized via a superficial hydrothermal method.
The prepared pristine Bi2S3, g-C3N4, and 3D-Bi2S3@2D-g-C3N4 composite samples were extensively studied for their
electrochemical performance and exhibited superior battery-type behaviors.
The results highlight that the optimized 3D-Bi2S3@2D-g-C3N4 composite sample exhibits a high
areal capacity of 41.53 μA h/cm2 at 1 mA/cm2 and a good rate capability of 62.77% along with a remarkable capacity
retention of 94.86% after 5000 cycles. The improved performance can
be attributed to the good beneficial features of the synergistic effect,
mesoporous structure, and lower dissolution. It offers a higher specific
surface area, enriches electroactive sites, increases electronic/ionic
conductivities, and reduces the interfacial resistance. Furthermore,
the solid-state symmetric supercapacitors (SSCs) were assembled by
two similar electrodes of 3D-Bi2S3@2D-g-C3N4 sandwiched between the KOH and PVA gel electrolyte.
The fabricated SSC device provides a high areal capacity of 25.40
μA h/cm2 at 1 mA/cm2. Furthermore, the
SSC delivers a maximum power density of 1495 μW/cm2 and an energy density of 3.17 μW h/cm2 with a good
cyclic retention of 83.84% after 7500 cycles. This work also demonstrates
the practical applicability of realizing red-light-emitting diodes
by interconnecting two SSCs in series.
The
large-scale usage of fungicides has been encountered with their
manifestations in various agro-food products. This causes several
detrimental impacts such as phytotoxicity and microbial resistance
that affect different levels of ecological organization, which call
for strict quantification of such toxic substances. In this work,
we report the synthesis of molybdenum carbide (Mo2C) MXene
on three-dimensional Globe Amaranth flower-like NiMn layered double-hydroxide
(NiMn-LDH) petal arrays that are intercalated with the CO3
2– backbone via a sustainable, scalable, and facile
synthetic hydrothermal route for the electrochemical detection of
carbendazim (CBZ). The fabricated electrode favors enlarged active
surface area, high electrical conductivity, rapid mass transport,
and ion diffusion that enhance the electrochemical performance toward
CBZ monitoring where the combined effects of NiMn-LDH and Mo2C provide improved electrochemical properties. Under optimum conditions,
the Mo2C@NiMn-LDH-modified electrode delivers static characteristics
such as wide dynamic linear response (0.001–232.14 μM),
low detection limit (0.2 nM), higher sensitivity (95.71 μA μM–1 cm–2), and good stability (30 cycles)
and reproducibility (5 electrodes). We further demonstrate the interference-free
sensing of CBZ by the Mo2C@NiMn-LDH sensor, suggesting
its feasibility for practical applications in real-world samples with
acceptable recovery ranges (water sample = ±97.50–99.43%
and vegetable extract samples = ±98.20–99.86%).
Potentially hazardous chemical contaminants endanger the environment and human well-being, challenging the scientists and policy-makers to develop holistic alternative approaches for remediation. The addition or accumulation of these chemicals can...
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