Realization of remote wearable health monitoring (RWHM) technology for the flexible photodiodes is highly desirable in remote-sensing healthcare systems used in space stations, oceans, and forecasting warning, which demands high external quantum efficiency (EQE) and detectivity in NIR region. Traditional inorganic photodetectors (PDs) are mechanically rigid and expensive while the widely reported solution-processed mixed tin-lead (MSP) perovskite photodetectors (PPDs) exhibit a trade-off between EQE and detectivity in the NIR region. Herein, a novel functional passivating antioxidant (FPA) strategy has been introduced for the first time to simultaneously improve crystallization, restrain Sn 2+ oxidization, and reduce defects in MSP perovskite films by multiple interactions between thiophene-2-carbohydrazide (TAH) molecules and cations/anions in MSP perovskite. The resultant solution-processed rigid mixed Sn-Pb PPD simultaneously achieves high EQE (75.4% at 840 nm), detectivity (1.8 × 10 12 Jones at 840 nm), ultrafast response time (t rise /t fall = 94 ns/97 ns), and improved stability. This work also highlights the demonstration of the first flexible photodiode using MSP perovskite and FPA strategy with remarkably high EQE (75% at 840 nm), and operational stability. Most importantly, the RWHM is implemented for the first time in the PIN MSP perovskite photodiodes to remotely monitor the heart rate of humans at rest and after-run conditions.
Application of light-emitting diodes (LEDs) based visible light communication (VLC) in underwater wireless communication has become a hot topic. However, on the one hand, the performance of underwater VLC (UVLC) system is limited due to power attenuation in water medium. On the other hand, increasing the driving power will induce nonlinearity from the imperfect optoelectronic components. Particularly at high signal amplitude, nonlinearity will become the dominant bottleneck. In this paper, we focus on nonlinearity mitigation method which preprocesses signal at transmitter-side. Multi-bit delta-sigma modulation combined carrier-less amplitude and phase modulation (DSM-CAP) is proposed to obtain quantized signal with lower peak-to-average power ratio (PAPR). Furthermore, as assuming the quantization noise being additive white noise is not appropriate in nonlinearity, modulus pruned weighted look-up table (MP-WLUT) is employed to modify the signal before DSM quantization to mitigate pattern dependent nonlinear distortion. Experimental results indicate that the DSM-CAP has better nonlinearity mitigating performance than normal CAP. At the data rate of about 1.69Gbp/s, utilizing MP-WLUT pre-distorted DSM-CAP an improvement of 1.44 dB Q-factor is realized compared with normal CAP without WLUT, and the size of MP-WLUT can be reduced to 62.5% of the full-size WLUT.
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