We report on deterministic generation of 18-qubit genuinely entangled Greenberger-Horne-Zeilinger (GHZ) state and multi-component atomic Schrödinger cat states of up to 20 qubits on a quantum processor, which features 20 superconducting qubits interconnected by a bus resonator. By engineering a one-axis twisting Hamiltonian enabled by the resonator-mediated interactions, the system of qubits initialized coherently evolves to an over-squeezed, non-Gaussian regime, where atomic Schrödinger cat states, i.e., superpositions of atomic coherent states including GHZ state, appear at specific time intervals in excellent agreement with theory. With high controllability, we are able to take snapshots of the dynamics by plotting quasidistribution Q-functions of the 20qubit atomic cat states, and globally characterize the 18-qubit GHZ state which yields a fidelity of 0.525 ± 0.005 confirming genuine eighteen-partite entanglement. Our results demonstrate the largest entanglement controllably created so far in solid state architectures, and the process of generating and detecting multipartite entanglement may promise applications in practical quantum metrology, quantum information processing and quantum computation.

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Nonequilibrium quantum many-body systems, which are difficult to study via classical computation, have attracted wide interest. Quantum simulation can provide insights into these problems. Here, using a programmable quantum simulator with 16 all-to-all connected superconducting qubits, we investigate the dynamical phase transition in the Lipkin-Meshkov-Glick model with a quenched transverse field. Clear signatures of dynamical phase transitions, merging different concepts of dynamical criticality, are observed by measuring the nonequilibrium order parameter, nonlocal correlations, and the Loschmidt echo. Moreover, near the dynamical critical point, we obtain a spin squeezing of −7.0 ± 0.8 dB, showing multipartite entanglement, useful for measurements with precision fivefold beyond the standard quantum limit. On the basis of the capability of entangling qubits simultaneously and the accurate single-shot readout of multiqubit states, this superconducting quantum simulator can be used to study other problems in nonequilibrium quantum many-body systems, such as thermalization, many-body localization, and emergent phenomena in periodically driven systems.

Engineered nanoparticles (NPs) are being released into aquatic environments with their increasing applications. In this work, we investigated the interaction of CuO NPs with a floating plant, water hyacinth (Eichhornia crassipes). CuO NPs (50 mg/L) showed significant growth inhibition on both roots and shoots of E. crassipes after 8-day exposure, much higher than that of the bulk CuO particles (50 mg/L) and their corresponding dissolved Cu ions (0.30 mg/L). Scanning electron and light microscopic observations showed that the root caps and meristematic zone of E. Crassipes were severely damaged after CuO NP exposure, with disordered cell arrangement and a destroyed elongation zone of root tips. It is confirmed that CuO NPs could be translocated to shoot from both roots and submerged leaves. As detected by X-ray absorption near-edge spectroscopy analysis (XANES), CuO NPs were observed in roots, submerged leaves, and emerged leaves. CuS and other Cu species were also detected in these tissues, providing solid evidence of the transformation of CuO NPs. In addition, stomatal closure was observed during CuO NPs-leaf contact, which was induced by the production of HO and increased Ca level in leaf guard cells. These findings are helpful for better understanding the fate of NPs in aquatic plants and related biological responses.

Quantum emulators, owing to their large degree of tunability and control, allow the observation of fine aspects of closed quantum many-body systems, as either the regime where thermalization takes place or when it is halted by the presence of disorder. The latter, dubbed many-body localization (MBL) phenomenon, describes the non-ergodic behavior that is dynamically identified by the preservation of local information and slow entanglement growth. Here, we provide a precise observation of this same phenomenology in the case the onsite energy landscape is not disordered, but rather linearly varied, emulating the Stark MBL. To this end, we construct a quantum device composed of thirty-two superconducting qubits, faithfully reproducing the relaxation dynamics of a non-integrable spin model. Our results describe the real-time evolution at sizes that surpass what is currently attainable by exact simulations in classical computers, signaling the onset of quantum advantage, thus bridging the way for quantum computation as a resource for solving out-of-equilibrium many-body problems.