Using bifunctional silica as a catalyst for graphitization and a templating agent for pore-formation, high graphitization and surface area are synchronously realized in porous N/P doped carbonaceous materials.
Finding out the catalysis trend is an important prerequisite for the development of advanced or untouched catalysts. Intermetallic silicides composed of interstitial Si and Pt-group metals (PGMs) are currently rarely reported as hydrogen evolution reaction (HER) catalysts due to the absence of accessibility and predictability. Herein, by theoretical calculations, we unveil the activity trend of PGM silicides and show that IrSi is the most efficient HER catalyst because of the appropriate d-band center and optimal adsorption behavior. Furthermore, we pioneer the use of the molten salt-assisted synthesis strategy to successfully synthesize a series of PGM silicides (IrSi, PtSi, Pd 2 Si, RhSi, and RuSi x ) under normal pressure and mild conditions by overcoming the slow diffusion of silicon (Si) and verify the generality of this strategy. Electrochemical evaluation demonstrates that IrSi indeed possesses excellent HER catalysis activity, outperforming the commercial Pt catalyst, with an ultralow overpotential of 24 mV to achieve 10 mA cm −2 in acidic media, and the predicted activity trend is further fitted experimentally. This work provides a valuable prediction result for catalysis and a feasible general method for construction of PGM silicides.
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