Recovery Cu(II) dan Pb(II) yang sebagian besar terkandung dalam limbah cair industri, baik industri besar maupun rumah tangga telah dilakukan, salah satunya adalah dengan proses adsorpsi. Penelitian ini dilakukan studi kinetika adsorpsi Cu(II) dan Pb(II) dalam limbah cair untuk mengetahui efektivitas biosorben dari ekstrak kulit buah rambutan terhadap limbah cair yang mengandung Cu(II) dan Pb(II). Penentuan kinetika adsorpsi Cu(II) dan Pb(II) dengan menggunakan biosorben dari ekstrak kulit buah rambutan dilakukan melalui beberapa model kinetika yaitu model kinetika Langmuir-Hinshelwood, Santosa, Lagergreen dan Ho. Kinetika adsorpsi Cu(II) dan Pb(II) semuanya mengikuti model kinetika Ho, yang merupakan mekanisme kinetika orde dua semu.
The research on synthesis of carbon from rice groats at various pyrolysis temperatures and its application for the recovery of chromium wastewater from the tannery industry by varying pyrolysis temperatures at 300, 400, and 500 °C. The results of carbon synthesis are analyzed in the form of determination of yield, water content, ash content, and iodine number. The best pyrolysis condition with the quality requirement of carbon is at a pyrolysis temperature of 500 °C with 760 mg.g-1 (iodine number). Adsorption kinetics was also carried out to determine the adsorption kinetics of chromium ions from tannery wastewater. Adsorption kinetics model of chromium wastewater from the tannery industry corresponds to the pseudo-second-order kinetics model with R2 is 0.9857, k2 is 0.0093 g.mg-1.min-1, and qe is 28.5714 mg.g-1.
The effect of temperature on the extraction process of nephelium peel in the modification nephelium tannin based biosorbent (NTBB) from the nephelium peel was done by varying the temperature of the extraction. Modified nephelium tannin based biosorbent carried by the cross-linker using formaldehyde and performed stability of nephelium tannin based biosorbent by varying the pH system. The results of cross-link process between tannin extract and formaldehyde compounds to produce nephelium tannin based biosorbent which were characterized using infrared spectrophotometer. The characterization result by infrared spectrophotometer shown extraction temperature of tannin from the nephelium peel affected the formation of nephelium tannin based biosorbent functional groups. The higher extraction temperature cause HCN will be released and attached on nephelium tannin based biosorbent polymer that was detected by IR spectra. The stability of nephelium tannin based biosorbent in solution shows that nephelium tannin based biosorbent will easily dissolve in the system of high acidity so that it will form a high peak at a wavelength of 240-280 nm using a UV-visible spectrophotometer, where nephelium tannin based biosorbent optimum stability in solution occurs at pH 5.
Ethoxy ethane, or diethyl ether, has been successfully synthesized through the condensation reaction of bioethanol produced from fruit waste fermentation using acid-activated H-Zeolite, H2SO4/H-Zeolite, and H2SO4 as catalysts. Zeolite activation was carried out using the acidification method with 1 M, 2 M, 4 M, and 6 M H2SO4 for 24 hours. Activated zeolites were characterized using infrared spectroscopy, X-ray diffraction, and NaOH titration. The condensation reaction of bioethanol was carried out by catalysis of H2SO4/H-Zeolite with various concentrations of 1 M, 2 M, 4 M, and 6 M and catalyzed by 2 M, 4 M, and 6 M acid-activated H-Zeolite. The condensation reaction process was carried out with a ratio of bioethanol to catalyst of 2:1 (w/w) using the fractional distillation method. Ethoxy ethane resulting from the condensation reaction was characterized using a GC instrument.
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