[1] Large sets of filtered actinometer, filtered pyrheliometer and Sun photometer measurements have been carried out over the past 30 years by various groups at different Arctic and Antarctic sites and for different time periods. They were examined to estimate ensemble average, long-term trends of the summer background aerosol optical depth AOD(500 nm) in the polar regions (omitting the data influenced by Arctic haze and volcanic eruptions). The trend for the Arctic was estimated to be between À1.6% and À2.0% per year over 30 years, depending on location. No significant trend was observed for Antarctica. The time patterns of AOD(500 nm) and Å ngström's parameters a and b measured with Sun photometers during the last 20 years at various Arctic and Antarctic sites are also presented. They give a measure of the large variations of these parameters due to El Chichon, Pinatubo, and Cerro Hudson volcanic particles, Arctic haze episodes most frequent in winter and spring, and the transport of Asian dust and boreal smokes to the Arctic region. Evidence is also shown of marked differences between the aerosol optical parameters measured at coastal and high-altitude sites in Antarctica. In situ optical and chemical composition parameters of aerosol particles measured at Arctic and Antarctic sites are also examined to achieve more complete information on the multimodal size distribution shape parameters and their radiative properties. A characterization of aerosol radiative parameters is also defined by plotting the daily mean values of a as a function of AOD(500 nm), separately for the two polar regions, allowing the identification of different clusters related to fifteen aerosol classes, for which the spectral values of complex refractive index and single scattering albedo were evaluated. Citation: Tomasi, C., et al. (2007), Aerosols in polar regions: A historical overview based on optical depth and in situ observations,

[1] During a 33-month measurement period at a high-latitude background site in northern Finland, a total of 103 new particle formation events were observed. In 19 cases, movement of the air masses allowed the observation of particle formation and growth over a sufficiently long time to investigate the production of ''potential'' cloud condensation nuclei (CCN) resulting from new-particle formation. All the CCN formation events took place in relatively clean air that had traversed the Northern Atlantic/Arctic Ocean prior to arrival at our measurement site. The number of formed new, ''potential'' CCN varied significantly between the different events and correlated weakly with the number of new-particles formed during the same events. This is consistent with recent theoretical suggestions of some sort of decoupling between atmospheric new-particle formation and growth. The vapours responsible for the ''potential'' CCN production could not be identified but were mostly something else than sulfuric acid resulting from the oxidation of SO 2 in the gas phase. Although atmospheric new-particle formation is likely to give only a minor contribution to the overall CCN budget at our measurement site, the situation may be different over areas where new-particle formation events are more common. At the very least, our results demonstrate that because of atmospheric new-particle formation, it may not be possible to find any universal relation between the aerosol mass and cloud droplet number concentration that is applicable to clean conditions.

Multi-year sets of ground-based sun-photometer measurements conducted at 12 Arctic sites and 9 Antarctic sites were examined to determine daily mean values of aerosol optical thickness () at visible and near-infrared wavelengths, from which best-fit values of Ångström"s exponent  were calculated. Analysing these data, the monthly mean values of (0.50 µm) and  and the relative frequency histograms of the daily mean values of both parameters were determined for winterspring and summer-autumn in the Arctic and for austral summer in Antarctica. The Arctic and Antarctic covariance plots of the seasonal median values of  versus (0.50 µm) showed: (i) a considerable increase in (0.50 µm) for the Arctic aerosol from summer to winter-spring, without marked changes in ; and (ii) a marked increase in (0.50 µm) passing from the Antarctic Plateau to coastal sites, whereas  decreased considerably due to the larger fraction of sea-salt aerosol. Good agreement was found when comparing ground-based sun-photometer measurements of () and  at Arctic and Antarctic coastal sites with Microtops measurements conducted during numerous AERONET/MAN cruises from 2006 to 2013 in three Arctic Ocean sectors and in coastal and offshore regions of the Southern Atlantic, Pacific, and Indian Oceans, and the Antarctic Peninsula. Lidar measurements were also examined to characterise vertical profiles of the aerosol backscattering coefficient measured throughout the year at Ny-Ålesund. Satellite-based MODIS, MISR, and AATSR retrievals of () over large parts of the oceanic polar regions during spring and summer were in close agreement with ship-borne and coastal ground-based sun-photometer measurements. An overview of the chemical composition of fine and accumulation/coarse mode particles is also presented, based on in-situ measurements at Arctic and Antarctic sites. Fourteen log-normal aerosol number size-distributions were defined to represent the average features of fine and accumulation/coarse mode particles for Arctic haze, summer background aerosol, Asian dust and boreal forest fire smoke, and for various background austral summer aerosol types at coastal 4 and high-altitude Antarctic sites. The main columnar aerosol optical characteristics were determined for all particle modes, based on in-situ measurements of the scattering and absorption coefficients. Diurnally averaged direct aerosol-induced radiative forcing and efficiency were calculated for a set of multimodal aerosol extinction models, using various Bidirectional Reflectance Distribution Function models over vegetation-covered, oceanic and snow-covered surfaces. These gave a reliable measure of the pronounced effects of aerosols on the radiation balance of the surface-atmosphere system over polar regions.

Abstract. We have measured spectral albedo, as well as ancillary parameters, of seasonal European Arctic snow at Sodankylä, Finland (67°22' N, 26°39' E). The springtime intensive melt period was observed during the Snow Reflectance Transition Experiment (SNORTEX) in April 2009. The upwelling and downwelling spectral irradiance, measured at 290–550 nm with a double monochromator spectroradiometer, revealed albedo values of ~0.5–0.7 for the ultraviolet and visible range, both under clear sky and variable cloudiness. During the most intensive snowmelt period of four days, albedo decreased from 0.65 to 0.45 at 330 nm, and from 0.72 to 0.53 at 450 nm. In the literature, the UV and VIS albedo for clean snow are ~0.97–0.99, consistent with the extremely small absorption coefficient of ice in this spectral region. Our low albedo values were supported by two independent simultaneous broadband albedo measurements, and simulated albedo data. We explain the low albedo values to be due to (i) large snow grain sizes up to ~3 mm in diameter; (ii) meltwater surrounding the grains and increasing the effective grain size; (iii) absorption caused by impurities in the snow, with concentration of elemental carbon (black carbon) in snow of 87 ppb, and organic carbon 2894 ppb, at the time of albedo measurements. The high concentrations of carbon, detected by the thermal–optical method, were due to air masses originating from the Kola Peninsula, Russia, where mining and refining industries are located.

This study determined measured and Mie-calculated angular signal truncations for total and backscatter TSI, Inc., nephelometers, as a function of wavelength and for particles of known size and composition. Except for the total scattering channels, similar agreements as in a previous study of measured and calculated truncations were derived for submicrometer test aerosols. For the first time, instrument responses were also determined for supermicrometer test aerosols up to 1.9 m in geometric mean diameter. These supermicrometer data confirm the theoretical predictions of strong angular truncations of the total scatter signals in integrating nephelometers due to the limited range of measured forward scattering angles. Truncations up to 60% were determined for the largest measured particles. Rough empirical truncation corrections have been derived from the calibration data for Radiance Research and Ecotech nephelometers for which no detailed response characteristics exist. Intercomparisons of the nephelometers measuring urban atmospheric aerosols yield average deviations of the slope from a 1:1 relation with a TSI reference nephelometer of less than 7%. Average intercepts range between ϩ0.53 and Ϫ0.19 Mm Ϫ1 . For the Radiance Research and Ecotech nephelometers ambient regressions of the Radiance Research and Ecotech instruments with the TSI nephelometer show larger negative intercepts, which are attributed to their less well characterized optics.