We present measurements of second- and higher-order intensity correlation functions (so-called Hanbury Brown-Twiss experiment) performed at the free-electron laser (FEL) FLASH in the non-linear regime of its operation. We demonstrate the high transverse coherence properties of the FEL beam with a degree of transverse coherence of about 80% and degeneracy parameter of the order 10(9) that makes it similar to laser sources. Intensity correlation measurements in spatial and frequency domain gave an estimate of the FEL average pulse duration of 50 fs. Our measurements of the higher-order correlation functions indicate that FEL radiation obeys Gaussian statistics, which is characteristic to chaotic sources.
WavePacket is an open-source program package for the numerical simulation of quantummechanical dynamics. It can be used to solve time-independent or time-dependent linear Schrödinger and Liouville-von Neumann-equations in one or more dimensions. Also coupled equations can be treated, which allows to simulate molecular quantum dynamics beyond the Born-Oppenheimer approximation. Optionally accounting for the interaction with external electric fields within the semiclassical dipole approximation, WavePacket can be used to simulate experiments involving tailored light pulses in photo-induced physics or chemistry. The graphical capabilities allow visualization of quantum dynamics 'on the fly', including Wigner phase space representations. Being easy to use and highly versatile, WavePacket is well suited for the teaching of quantum mechanics as well as for research projects in atomic, molecular and optical physics or in physical or theoretical chemistry. The present Part I deals with the description of closed quantum systems in terms of Schrödinger equations. The emphasis is on discrete variable representations for spatial discretization as well as various techniques for temporal discretization. The upcoming Part II will focus on open quantum systems and dimension reduction; it also describes the codes for optimal control of quantum dynamics. The present work introduces the MATLAB version of WavePacket 5.2.1 which is hosted at the Sourceforge platform, where extensive Wiki-documentation as well as worked-out demonstration examples can be found. Programming language: Matlab Supplementary material: n. a. Journal reference of previous version: n. a. Does the new version supersede the previous version?: n. a. Reasons for the new version: n. a. Summary of revisions: n. a.* Nature of problem: Schrödinger's equations are of fundamental importance in non-relativistic quantum mechanics of distinguishable particles. The solutions of the time-independent equation (TISE) are wavefunctions in coordinate space, the absolute squares of which are usually interpreted as probability density. The time-dependent equation (TDSE) describes the dynamics of a quantum system evolving in time. It plays a crucial role for the simulation, understanding, and prediction of modern experiments in atomic, molecular and optical physics where systems are driven by temporally shaped external fields.
Solution method:All numerical methods compiled in WavePacket are based on discrete variable representations.Currently implemented are Gauss-Hermite, Gauss-Legendre and FFT-based schemes. The TISE is solved either by direct diagonalization or by propagation in imaginary time. For the TDSE there is a choice between second order differencing, operator splitting and Chebychev polynomial methods.
Additional comments including Restrictions and Unusual features:The WavePacket program package is rather easy and intuitive to use, providing visualization of quantum dynamics 'on the fly'. It is mainly intended for low-dimensional systems, typically not exceeding three t...
In single-particle coherent x-ray diffraction imaging experiments, performed at x-ray free-electron lasers (XFELs), samples are exposed to intense x-ray pulses to obtain single-shot diffraction patterns. The high intensity induces electronic dynamics on the femtosecond time scale in the system, which can reduce the contrast of the obtained diffraction patterns and adds an isotropic background. We quantify the degradation of the diffraction pattern from ultrafast electronic damage by performing simulations on a biological sample exposed to x-ray pulses with different parameters. We find that the contrast is substantially reduced and the background is considerably strong only if almost all electrons are removed from their parent atoms. This happens at fluences of at least one order of magnitude larger than provided at currently available XFEL sources.
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