Abstract. Stable isotopes (deuterium, 2 H, and oxygen-18, 18

The isotopic signature of soil water is influenced by mineral-water interaction. During the hydration of clay, different minerals deplete free water in heavy isotopes. The extracted soil water (dehydration water) gathered from clay-rich soils is generally more depleted in the heavy isotopes than the spike water, making results obtained for different soil types difficult to compare. Isotope effects observed at the mineral-water interface highlight potential explanations for eco-hydrological separation of water pools. Copyright © 2016 John Wiley & Sons, Ltd.

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Groundwater recharge estimations are necessary for sustainable management of groundwater resources. Among various hydraulic, hydrogeological and hydrological approaches, tracer methods are proposed to improve groundwater recharge estimations. Soil water isotope‐based estimates of groundwater recharge rates were developed in the 1960s and have been applied in more than 40 studies reviewed within this manuscript. This comprehensive review research distinguishes three fundamental research approaches: (1) labelling method with tritium or deuterium, which can be used to trace unsaturated zone water movement, (2) tracing soil water movement using a seasonal signal of stable isotopes in precipitation, mainly applied in humid zones, and (3) interpretation of an evaporation signal that impacts soil water stable isotope composition, mainly applicable in arid and semiarid regions. More recently, advances in soil water extraction and analytical methods allow a higher sampling resolution and in situ measurements of soil water stable isotopes. Analytical advances may strengthen and improve the applicability of stable isotope methods for quantitative recharge. We present, compare and discuss studies of unsaturated zone isotope profiles with an emphasis on necessary prerequisites, such as a substantial thick porous sedimentary layer, or negative influences through high clay and silt contents or dry soil conditions. Copyright © 2015 John Wiley & Sons, Ltd.

The results of field tracer experiments performed in the Lindau fractured rock test site (southern Black Forest, Germany) and subsequent modeling are presented. A vertical, hydrothermally mineralized fault zone, with a permeability much greater than the surrounding granite mass, lies beneath a planned dam site. A dense network of boreholes and tunnels were used to investigate scaling effects of solute transport processes in fractured rock. A series of tracer experiments using deuterium and dye tracers (uranine, eosine, and pyranine) were performed over varying distances and under different testing procedures, resulting in different flow field conditions. Large‐scale tracer experiments (21 to 346 m) were performed under natural flow field conditions, while small‐scale tracer experiments (11 to 16 m) were performed under artificially induced radial‐convergent and injection‐withdrawal flow fields. The tracer concentration curves observed in all experiments were strongly influenced by the matrix diffusion. The curves were evaluated with the one‐dimensional single fissure dispersion model (SFDM) (advective‐dispersive transport in the fractures coupled with diffusive transport in the adjacent rock matrix) adjusted for the different flow field conditions. The fitting model parameters found determined the fracture aperture, and matrix and fissure porosities. The determined fracture aperture varied between the sections having different hydraulic conductivities (100 to 270 um and 430 to 580 um, respectively). The determined values of matrix porosity (3 to 7%) seemed to be independent of the scale of the experiment. The modeled matrix porosities agreed well with values determined in independent laboratory investigations of drill cores using mercury porosimetry. In situ fissure porosity, determined only in small‐scale experiments, was independent of the applied geometry of the artificially induced flow fields. The dispersivities were found to be independent of the scale of experiment but dependent on the flow conditions. The values found in forced gradient tests lie between 0.2 and 0.3 m, while values in experiments performed under natural flow conditions were one order of magnitude higher.