Keywords: Zinc / Cadmium / N,S ligands / Structure elucidation / Enzyme models / Coordination modes Two different modes of binding methanol and ethanol were found in crystals of heteroleptic zinc and cadmium complexes with MS 2 NO 2 and MS 2 NO kernels and with a general formula M(RS) 2 (im) (M = Zn, Cd; RS = tri-tert-butoxysilanethiolate; im = imidazole, 2-methylimidazole, 2-ethylimidazole). Alcohol molecules are either trapped in the crystal lattice by NH···O and OH···S hydrogen bonds or directly coordinated to the metal centre. The complexes were studied by X-ray diffraction, solid state FTIR and
Two new methylsilylsulfides are synthesized. Propeller-like chirality is described for triaryloxysilanethiol and its methyl derivative. S-methylation of the silanethiol lowers the overall symmetry of the unit cell.
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