Graphene and graphene oxide (GO), as wonder materials, have penetrated nearly every field of research. One of their most attractive features is the functionality and assembly of graphene or GO, in which they can be considered to be chemically functionalized building blocks for creating unconventional porous graphene materials (PGMs) that not only combine the merits of both porous materials and graphene, but also have major advantages over other porous carbons for specific applications. The chemistry and approaches for functionalizing graphene and GO are first introduced, and typical procedures for pore creation (e.g., in-plane pores, 2D laminar pores, and 3D interconnected pore assemblies), self-assembly, and tailoring mechanisms for PGMs to highlight the significance of precise control over the pore morphology and pore size are summarized. Because of their unique pore structures, with different morphologies and intriguing properties, PGMs serve as key components in a variety of applications such as energy storage, electrocatalysis, and molecular separation. Finally, the challenges relating to PGMs from the understanding of chemical self-assembly to specific applications are discussed, and promising solutions on how to tackle them are presented. This provides an insightful outlook for the future development of the chemistry and applications of PGMs.

N-doped amorphous carbon coated Fe3O4/SnO2 coaxial nanofibers were prepared via a facile approach. The core composite nanofibers were first made by electrospinning technology, then the shells were conformally coated using the chemical bath deposition and subsequent carbonization with polydopamine as a carbon source. When applied as a binder-free self-supported anode for lithium ion batteries, the coaxial nanofibers displayed an enhanced electrochemical storage capacity and excellent rate performance. The morphology of the interwoven nanofibers was maintained even after the rate cycle test. The superior electrochemical performance originates in the structural stability of the N-doped amorphous carbon shells formed by carbonizing polydopamine.

Drought has become a major threat to local sustainable development in dryland Asia, one of the largest grassland ecosystems in the world. However, empirical-and science-based evidence regarding the extent of drought changes and the future trends of these changes in dryland Asia is variable and incomplete. Here, we first investigate the historical variations in drought conditions in dryland Asia, as measured by the drought intensity and arid area, using three widely used drought indices (the Palmer Drought Severity Index, the Standardized Precipitation Index, and the Standardized Precipitation Evapotranspiration Index). Then, we use Bayesian model averaging to reproduce the future drought conditions under two representative concentration pathways (RCP2.6 and RCP4.5) from the Coupled Model Intercomparison Project Phase 5 Earth system models. The Palmer Drought Severity Index, Standardized Precipitation Index, and Standardized Precipitation Evapotranspiration Index illustrate that dryland Asia has experienced an overall drying trend and an expansion of arid areas over the past 100 years (1901-2016). Both temperature and precipitation are projected to increase under both the 1.5 and 2.0°C warming scenarios compared with the values from the reference period (1986-2005). The projected drought conditions in the 1.5 and 2.0°C warming scenarios will worsen, especially across Kazakhstan and Northwest China. We found that the drought conditions under the 2.0°C warming conditions will not be as severe as those under the 1.5°C warming conditions due to the mitigating effect of the projected precipitation increase under RCP4.5. These results call for short-term and long-term mitigation and adaptation measurements for drought events in dryland Asia. Plain Language Summary To avoid the negative impacts of climate warming, the Paris Agreement aims to pursue efforts to maintain the global warming increase at well below 1.5 and even 2.0°C until the end of the century. Questions have been raised regarding the climate extremes in dryland Asia. Will drought issues become more severe under the context of global warming? Are the existing drought indices able to quantify and characterize the drought intensity and arid area in this region? Answers to these questions are crucial for the livelihood of millions of individuals, as these people rely on grassland biomass to feed both animals and farmers; however, the answers remain unclear. Here, we found that the projected drought severity and arid area will persistently increase under both the 1.5 and 2.0°C global warming scenarios. We also found that the drought conditions under the 2.0°C warming scenario will be mitigated relative to those under the 1.5°C warming scenario due to the beneficial effect of adequate precipitation under representative concentration pathway 4.5. Kazakhstan and Northwest China might be severely affected by drought. Therefore, understanding future changes in drought conditions in dryland Asia is critical for developing adaptation measures to cope with the challenge...