For the first time, a mononuclear cobalt(ii) complex with dicyanamide coligands exhibiting reversible spin crossover behavior at high temperature is reported.
The three mononuclear cobalt(II) complexes, [Co(L)(NCX)2] (L = N,N'-di-tert-butyl-2,11-diaza[3,3](2,6)pyridinophane, and X = S (1), Se (2), and [C(CN)2] (3)), have been synthesized and characterized using variable temperature single-crystal X-ray crystallography,...
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