Functionalized nanoporous carbon materials have attracted the colossal interest of the materials science fraternity owing to their intriguing physical and chemical properties including a well-ordered porous structure, exemplary high specific surface areas, electronic and ionic conductivity, excellent accessibility to active sites, and enhanced mass transport and diffusion. These properties make them a special and unique choice for various applications in divergent fields such as energy storage batteries, supercapacitors, energy conversion fuel cells, adsorption/separation of bulky molecules, heterogeneous catalysts, catalyst supports, photocatalysis, carbon capture, gas storage, biomolecule detection, vapour sensing and drug delivery. Because of the anisotropic and synergistic effects arising from the heteroatom doping at the nanoscale, these novel materials show high potential especially in electrochemical applications such as batteries, supercapacitors and electrocatalysts for fuel cell applications and water electrolysis. In order to gain the optimal benefit, it is necessary to implement tailor made functionalities in the porous carbon surfaces as well as in the carbon skeleton through the comprehensive experimentation. These most appealing nanoporous carbon materials can be synthesized through the carbonization of high carbon containing molecular precursors by using soft or hard templating or non-templating pathways. This review encompasses the approaches and the wide range of methodologies that have been employed over the last five years in the preparation and functionalisation of nanoporous carbon materials via incorporation of metals, non-metal heteroatoms, multiple heteroatoms, and various surface functional groups that mostly dictate their place in a wide range of practical applications.
Synthesis and excellent photocatalytic H2 evolution performance of diaminotetrazine based highly ordered 3D mesoporous carbon nitrides (MCN-9) with C3N6 stoichiometry prepared by employing KIT-6 silica template has been demonstrated.
Highly ordered mesoporous C with a well-ordered porous structure and a high crystallinity is prepared through the nanohard templating method using a saturated solution of C in 1-chloronaphthalene (51 mg mL ) as a C precursor and SBA-15 as a hard template. The high solubility of C in 1-chloronaphthalene helps not only to encapsulate a huge amount of the C into the mesopores of the template but also supports the oligomerization of C and the formation of crystalline walls made of C . The obtained mesoporous C exhibits a rod-shaped morphology, a high specific surface area (680 m g ), tuneable pores, and a highly crystalline wall structure. This exciting ordered mesoporous C offers high supercapacitive performance and a high selectivity to H O production and methanol tolerance for ORR. This simple strategy could be adopted to make a series of mesoporous fullerenes with different structures and carbon atoms as a new class of energy materials.
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