Rivers and ponds near the Erdenet mine, one of the world's largest copper-molybdenum mines, exhibit high concentrations of molybdenum (Mo). This study evaluates the distribution and chemical speciation of Mo in surface sediments from ponds and rivers in Erdenet city to elucidate the mobility and solubility of Mo in the surface aquatic environments in the area. The waters and sediments were collected in two shallow ponds connected to the tailing pond and from three rivers flowing through Erdenet city. The distribution and chemical speciation of Mo in the sediments were examined using five-step sequential extraction and X-ray absorption fine structure (XAFS) analyses. The XAFS spectra of the sediments showed that large amounts of Mo in the sediments are molybdate or polymeric molybdate, weakly adsorbed onto ferrihydrite. Sequential extraction consistently showed a large amount of Mo distributed in the labile fractions. Results suggest that the surface sediments from ponds and rivers play a role as secondary contamination sources of Mo rather than as sinks of Mo in the area.

The aim of the present study was to evaluate human health and potential ecological risk assessment in the ger district of Ulaanbaatar city, Mongolia. To perform these risk assessments, soil samples were collected based on reference studies that investigated heavy element distribution in soil samples near the ger area in Ulaanbaatar city. In total, 42 soil samples were collected and 26 heavy metals were identified by inductively coupled plasma optical emission spectrometry (ICP-OES) and inductively coupled plasma mass spectrometry (ICP-MS) methods. The measurement results were compared with the reference data in order to validate the soil contamination level. Although there was a large difference between the measurement results of the present and reference data, the general tendency was similar. Soil contamination was assessed by pollution indexes such as geoaccumulation index and enrichment factor. Mo and As were the most enriched elements compared with the other elements. The carcinogenic and noncarcinogenic risks to children exceeded the permissible limits, and for adults, only 12 out of 42 sampling points exceeded the permissible limit of noncarcinogenic effects. According to the results of the ecological risk assessment, Zn and Pb showed from moderate to considerable contamination indexes and high toxicity values for ecological risk of a single element. The Cr and As ranged as very high ecological risk than that of the other measured heavy metals.

No abstract