Cyclodextrins (CDs), one of the host molecules in supramolecular chemistry, can host guest molecules to form inclusion complexes via non-covalent and reversible host-guest interactions. CD-based light-responsive supramolecular systems are typically constructed using CDs and guest molecules with light-responsive moieties, including azobenzene, arylazopyrazole, o-nitrobenzyl ester, pyrenylmethyl ester, coumarin, and anthracene. To date, numerous efforts have been reported on the topic of CD-based light-responsive supramolecular systems, but these have not yet been highlighted in a separated review. This review summarizes the efforts reported over the past ten years. The main text of this review is divided into five sections (vesicles, micelles, gels, capturers, and nanovalves) according to the formation of self-assemblies. This feature article aims to afford a comprehensive understanding of the light-responsive moieties used in the construction of CD-based light-responsive supramolecular systems and to provide a helpful guide for the further design of CD-based light-responsive supramolecular systems.
In this paper, we investigate the sum-rate maximization of cellular users (CUs) and device-todevice (D2D) pairs for the D2D communications underlaying cellular networks over the Nakagami-m fading channel. We consider a resource-abundant scenario where the number of CUs is more than that of D2D pairs and discuss the joint optimization of signal-to-interference-plus-noise ratio (SINR) thresholds and CU-D2D pairing. We formulate the problem as mixed-integer non-linear programming, which is NP-hard in general. To solve the problem, we propose a two-step approach. First, we add virtual D2D pairs to make the number of D2D pairs equal to that of CUs and derive the near-optimal SINR threshold for each possible CU-D2D pairing by the simulated annealing algorithm. Second, the optimal CU-D2D pairing can be obtained by the Hungarian (HG) algorithm. The simulation results show that: 1) the proposed SINR policy outperforms the other policies by about 11.3%-63.4% and 2) compared with several state-of-the-art resource allocation policies, HG allocation can achieve an average sum-rate improvement of 10.9%-72.8%.
scite is a Brooklyn-based startup that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.