A composite of graphene oxide supported by needle-like MnO(2) nanocrystals (GO-MnO(2) nanocomposites) has been fabricated through a simple soft chemical route in a water-isopropyl alcohol system. The formation mechanism of these intriguing nanocomposites investigated by transmission electron microscopy and Raman and ultraviolet-visible absorption spectroscopy is proposed as intercalation and adsorption of manganese ions onto the GO sheets, followed by the nucleation and growth of the crystal species in a double solvent system via dissolution-crystallization and oriented attachment mechanisms, which in turn results in the exfoliation of GO sheets. Interestingly, it was found that the electrochemical performance of as-prepared nanocomposites could be enhanced by the chemical interaction between GO and MnO(2). This method provides a facile and straightforward approach to deposit MnO(2) nanoparticles onto the graphene oxide sheets (single layer of graphite oxide) and may be readily extended to the preparation of other classes of hybrids based on GO sheets for technological applications.
Two-dimensional metal-organic frameworks represent a family of materials with attractive chemical and structural properties, which are usually prepared in the form of bulk powders. Here we show a generic approach to fabricate ultrathin nanosheet array of metal-organic frameworks on different substrates through a dissolution–crystallization mechanism. These materials exhibit intriguing properties for electrocatalysis including highly exposed active molecular metal sites owning to ultra-small thickness of nanosheets, improved electrical conductivity and a combination of hierarchical porosity. We fabricate a nickel-iron-based metal-organic framework array, which demonstrates superior electrocatalytic performance towards oxygen evolution reaction with a small overpotential of 240 mV at 10 mA cm−2, and robust operation for 20,000 s with no detectable activity decay. Remarkably, the turnover frequency of the electrode is 3.8 s−1 at an overpotential of 400 mV. We further demonstrate the promise of these electrodes for other important catalytic reactions including hydrogen evolution reaction and overall water splitting.
To address the aggravating energy and environment issues, the cheap, highly active, and durable electrocatalysts as noble metal substitutes both at the anode and cathode are actively pursued. Among them, heteroatom-doped graphene-based materials show extraordinary electrocatalytic performance, some even close to or outperforming the state-of-the-art noble metals such as Pt and IrO 2 -based materials. This review provides a concise appraisal on graphene doping methods, the possible doping configurations and their unique electrochemical properties, including single-and double-doping with N, B, S, and P. In addition, heteroatom-doped graphene-based materials are reviewed as electrocatalysts for oxygen reduction (ORR), hydrogen evolution (HER), and oxygen evolution reactions (OER) in terms of their electrocatalytic mechanisms and performance. Significantly, three-dimensional (3D) heteroatom-doped graphene structures have been discussed, especially those that can be directly utilized as catalyst electrodes without extra binders and supports.
Pt-free electrocatalysts for hydrogen evolution reaction (HER) with high activity and low price are desirable for many state-of-the-art renewable energy devices, such as water electrolysis and photoelectrochemical water splitting cells. However, the design and fabrication of such materials remain a significant challenge. This work reports the preparation of a flexible three-dimensional (3D) film by integrating porous C3N4 nanolayers with nitrogen-doped graphene sheets, which can be directly utilized as HER catalyst electrodes without substrates. This nonmetal electrocatalyst has displayed an unbeatable HER performance with a very positive onset-potential close to that of commercial Pt (8 mV vs 0 mV of Pt/C, vs RHE @ 0.5 mA cm(-2)), high exchange current density of 0.43 mA cm(-2), and remarkable durability (seldom activity loss >5000 cycles). The extraordinary HER performance stems from strong synergistic effect originating from (i) highly exposed active sites generated by introduction of in-plane pores into C3N4 and exfoliation of C3N4 into nanosheets, (ii) hierarchical porous structure of the hybrid film, and (iii) 3D conductive graphene network.
A three-dimensional (3D) electrode composed of nitrogen, oxygen dualdoped graphene-carbon nanotube hydrogel film is fabricated, which greatly favors the transport and access of gas and reaction intermediates, and shows a remarkable oxygen-evolution catalytic performance in both alkaline and acidic solutions.
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