The investigations of the nonlinear optical parameters of Au, Ag, Pt and Cu colloidal solutions using the Z-scan method and third-harmonic generation (THG) are presented. The nonlinear refractive indices, nonlinear absorption coefficients and Kerr-induced nonlinear susceptibilities (χ(3)(-ω;ω,-ω,ω)) of these solutions on the wavelengths of picosecond and nanosecond Nd:YAG laser radiation (λ = 1064 nm) and its second harmonic (λ = 532 nm) have been measured. A tenfold increase of nonlinear susceptibilities on the wavelength of 532 nm in comparison with λ = 1064 nm is shown for these colloidal metals. The application of colloidal metals as optical limiters of picosecond and nanosecond radiation (λ = 1064 nm and 532 nm) was studied. The influence of aggregation of colloidal clusters on optical limiting in these media was considered. It was shown that the appearance of the long-wave wing of absorption at the final stages of aggregation led to the nonlinear absorption of picosecond pulses. The investigations of the THG of picosecond Nd:YAG laser radiation in colloidal metals (Pt and Cu) are presented. THG efficiency was found to be 7×10-7 for colloidal platinum. Nonlinear susceptibilities χ(3)(-3ω;ω,ω,ω) of colloidal platinum and copper were measured to be (1.5±0.75)×10-14 esu and (1±0.5)×10-14 esu, respectively.

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