Although zeolites and related materials combine nanoporosity with high thermal stability, they are difficult to modify or derivatize in a systematic way. A highly porous metal coordination polymer [Cu3(TMA)2(H2O)3]n (where TMA is benzene-1,3,5-tricarboxylate) was formed in 80 percent yield. It has interconnected [Cu2(O2CR)4] units (where R is an aromatic ring), which create a three-dimensional system of channels with a pore size of 1 nanometer and an accessible porosity of about 40 percent in the solid. Unlike zeolites, the channel linings can be chemically functionalized; for example, the aqua ligands can be replaced by pyridines. Thermal gravimetric analysis and high-temperature single-crystal diffractometry indicate that the framework is stable up to 240 degreesC.

A series of ten 2,3,4,5-tetraphenylsiloles with different 1,1-substituents [XYSi(CPh)4] were prepared, and three of these, i.e., 1,1,2,3,4,5-hexaphenylsilole [X = Y = Ph (3)], 1-ethynyl-1,2,3,4,5-pentaphenylsilole [X = Ph, Y = C⋮CH (15)], and 1,1-bis(phenylethynyl)-2,3,4,5-tetraphenylsilole [X = Y = C⋮CPh (18)], were characterized crystallographically. The ground- and excited-states of the siloles were influenced by the inductive effect of the 1,1-substituents:  with an increase in their electronegativity, the absorption and emission spectra of the siloles bathochromically shifted. A simple and reliable TLC-based method was developed for measurement of the solid-state luminescence spectra of the siloles. When molecularly dissolved in common solvents at room temperature, all the siloles were practically nonemissive (“off”). When poor solvents were added, the silole molecules clustered into nanoaggregates, which turned the emission “on” and boosted the photoluminescence quantum yields by up to 2 orders of magnitude (aggregation-induced emission). The silole emission could also be greatly enhanced by increasing the viscosity and decreasing the temperature of the silole solutions. The solution thickening and cooling experiments suggest that the aggregation-induced emission is caused by the restricted intramolecular rotations of the peripheral aromatic rings upon the axes of the single bonds linked to the central silole cores.