Inhibition of low carbon steel (LCS) corrosion in 3.5% NaCl of Pluchea indica Less. leaves extract (PILLE) has been studied using various investigation techniques such as weight loss and polarization methods. The percentage of inhibition increased as the concentration of the inhibitor increased. The results of corrosion test reveal that the extract behaves as a mixed type corrosion inhibitor. Optimum inhibition is reached from 3 mL gambir extract for immersion time of 216 hours. Fourier transform infrared (FTIR) spectroscopy result of adsorbed film on LCS surface containing PILLE shows that in changes in the functional group frequencies of the organic component of the extract.
Abstract. The effect and mechanism of green corrosion inhibitor of Morinda Citrifolia (Noni) toward low carbon steel material has been researched. The general background is to develop the cheap and eco-friendly corrosion inhibitor based on components taken from tropical plants that grow +in Indonesia. This research aims to determine the effectiveness of the use of the extracts of noni as green corrosion inhibitor of carbon steel material in aggressive environment. The medium applied for this experiment is 3.5% natrium chloride solution. The variation of the concentration and immersion time duration has been applied as the experimental parameters. All the work was done at room temperature. The corrosion rate was measured by electrochemical polarization method with CMS 600-Gamry instruments and weight loss. The adsorption of inhibitor into the metal surface, which induced bonding formation after immersion was observed by using FTIR method. Inhibition mechanism was observed by polarization curves and fitted by the Langmuir adsorption models. The experimental results show that the higher concentration of inhibitor increasing the inhibition effect. The optimum inhibition is obtained at 3 ppm noni fruit extract, after immersion for about 288 hours. The corrosion rates obtained was 1.385 mpy, with the inhibitor efficiency of 76.92%. The monolayer film is formed coating the surface material as a result of mixed type corrosion inhibitor behavior of Noni. It can be concluded that this green inhibitor is effective to be used for low carbon steel material.
Plate spacing is one of variable that influences plate heat exchanger (PHE) design as a condenser in Organic Rankine Cycle (ORC) system. The rises of plate spacing have effects to channel cross sectional area, channel velocity, equivalent diameter, and Reynold number at hot and cold fluid sides in PHE. Those parameters affect the total heat transfer area and total pressure drop that influence the PHE condenser performance. This paper investigated the detail effect of the plate spacing increments in the final total heat transfer area and total pressure drop design result. The plate spacing in design calculation method is varied and the other independent variables are assumed to be constant. The design was conducted by calculating condenser capacity at both sides and both zones, estimating overall heat transfer coefficient, and calculating heat transfer area and plate film coefficient. Analysis continued by calculating overall heat transfer coefficient that has small percent of error with the estimated overall heat transfer coefficient, calculating pressure drop, total plate number and total heat transfer area. The result of calculation shows that the rises of plate spacing increase the total heat transfer area and decrease the cold and hot fluid total pressure drop. The rises of plate spacing increase channel cross sectional area and equivalent diameter, and decrease channel velocity and Reynold number at zone 1 (without phase change) and zone 2 (with phase change). Therefore, the increment of heat transfer areas is unpreferable and the decrement of pressure drops is preferable.
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