The emission properties of carbon dots (CDs) have already found many potential applications, from bio-imaging and cell labelling, to optical imaging and drug delivery, and are largely investigated in technological fields, such as lighting and photonics. Besides their high efficiency emission, CDs are also virtually nontoxic and can be prepared through many green chemistry routes. Despite these important features, the very origin of their luminescence is still debated. In this paper, we present an overview of sounding data and the main models proposed to explain the emission properties of CDs and their tunability.

Surface in porous media has a key role for both theoretical and technological aspects. A comparative analysis of the surface vibrational properties of sol−gel synthesized porous silica monoliths with different porosity is presented. Raman spectroscopy investigation of the fundamental O−H stretching range (3000−3800 cm-1) reveals a dependence of the surface reactivity on pore dimensions. The pore surface curvature plays an important role affecting the hydrogen-bonding interaction between surface hydroxyls and modifying the distribution of the OH species at the surface; the relative contribution of interacting hydroxyls and adsorbed water with respect to isolated species is larger in smaller pores. Water and silanol vibrations were singled out as a function of porosity.

Biomedical application of nanoparticles is largely associated to their fate in biological media which, in turn, is related to their surface properties. Surface functionalization plays a key role in determining biodegradation, cytotoxicity and biodistribution through interactions which may be mediated by the macromolecules occurring in biological media. A typical example is given by several proteins which lead to the formation of coated nanoparticles referred as protein corona. In this work we focus on mesoporous silica nanoparticles which, due to their intrinsic textural features, show potential as carriers for sustained drug release. Mesoporous silica nanoparticles functionalized by different biopolymers such as hyaluronic acid and chitosan were synthesized and characterized through small angle X-rays scattering, thermal analysis, and infrared spectroscopy. Biopolymer-coated mesoporous silica nanoparticles were used to investigate the interaction with bovine serum albumin, and to point out the role of different biopolymer coating. Gold-conjugated-bovine serum albumin was used to gain evidence on the occurrence of surface bound proteins enabling direct observation by transmission electron microscopy. Our findings provide insights on how different biopolymers affect the formation of a protein corona around functionalized mesoporous silica nanoparticles.

Carbon Nitride and its polymorphs have recently gained large interests for their huge properties and applications in different fields, from lighting to photocatalysis. Further, several attempts were recently devoted to tune and control its optical and electrical properties. In this report we analyze phenyl modified Carbon Nitride structures obtained by simple thermal polymerization at different temperatures (250-400°C) of the starting precursor: 2,4diamino-6-phenyl-1,3,5-triazine. A multi-technique experimental data (XRD patterns, Raman, TGA and DTG, steady-time and time resolved Luminescence, Photoluminescence Excitation spectra, Reflectivity spectra) was applied to analyze the relationship between structural and optical properties and to give more insight on the effect of synthesis procedure on the final polymer. The optical properties evidenced an interesting shift towards the visible region of the absorption spectrum of the phenyl modified g-C 3 N 4 polymer that, associated with the high optical quantum yield (about 60%) and to a broad emission in the green-red spectral region, makes the samples very suitable for lighting applications. Indeed, we report a first prototype of white LED emission by assembly of a commercial blue LED and the Phenyl modified g-C 3 N 4 powders as phosphor, verifying the structural and optical stability over about 10,000 working hours.

Carbon nanodots (CNDs) are the latest and most shining rising stars among photoluminescent (PL) nanomaterials. These carbon-based surface-passivated nanostructures compete with other related PL materials, including traditional semiconductor quantum dots and organic dyes, with a long list of benefits and emerging applications. Advantages of CNDs include tunable inherent optical properties and high photostability, rich possibilities for surface functionalization and doping, dispersibility, low toxicity, and viable synthesis (top-down and bottom-up) from organic materials. CNDs can be applied to biomedicine including imaging and sensing, drug-delivery, photodynamic therapy, photocatalysis but also to energy harvesting in solar cells and as LEDs. More applications are reported continuously, making this already a research field of its own. Understanding of the properties of CNDs requires one to go to the levels of electrons, atoms, molecules, and nanostructures at different scales using modern molecular modeling and to correlate it tightly with experiments. This review highlights different in silico techniques and studies, from quantum chemistry to the mesoscale, with particular reference to carbon nanodots, carbonaceous nanoparticles whose structural and photophysical properties are not fully elucidated. The role of experimental investigation is also presented. Hereby, we hope to encourage the reader to investigate CNDs and to apply virtual chemistry to obtain further insights needed to customize these amazing systems for novel prospective applications.

Complex [Pt(iPr pipdt)(Quinoxdt)] (iPr pipdt=1,4-diisopropyl-piperazine-2,3-dithione; Quinoxdt=[1,4]dithiino[2,3-b]quinoxaline-2,3-dithiolate) exhibits a remarkable green emission at 570 nm (room temperature), which is above the lowest excited state. The complex is characterized by negative solvatochromism as well as a high second-order polarizability. Addition of Ag ions induces 1) hypsochromic shift of the lowest frequencies and 2) reversible quenching of luminescence. The corresponding Ni and Pd complexes have also been prepared and investigated to assist interpretation of optical properties within the triad. Computational studies based on DFT and time-dependent DFT highlight the electronic properties of [Pt(iPr pipdt)(Quinoxdt)]. The preferential site of interaction between the Pt complex and incoming Ag is evidenced by the shape of the Fukui functions, pointing to the thiolic sulfur and platinum atoms as the most reactive sites towards a soft cation. Calculated optical properties are in agreement with experimental findings. This study sheds light on the structure-property relationship for this class of compounds.

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Assuring high quality of water is an urgent challenge for today’s research. In spite of the enormous progresses achieved in the area, the quest for all-in-one systems able to adsorb,...