Retrievals obtained after revision surgery, provide valuable information on the rate of wear and the causes of wear that take place in vivo. The aim of this study was to perform a root cause failure analysis to determine the principle reason for mechanical failure on failed acetabular cups, retrieved during revision surgery, by making use of sound engineering failure analysis techniques. The bearing couples varied between steel on UHMWPE and ceramic on UHMWPE. The information gained during this analysis brought to the four that the principle mode of mechanical failure for acetabular cups is overheating of the UHMWPE. The resulting overheating is mainly due to a lack of good and/or sufficient lubrication.
Organo-bentonites containing quaternary ammonium surfactants were prepared using purified bentonite from the Boane deposit in Mozambique. The intercalation was effected by intimate mixing of the surfactants into a concentrated dispersion of soda ash activated bentonite. TG indicated organic contents that exceeded CEC expectations by up to 21 mass %. XRD results were consistent with: (i) paraffin-type extended chain intercalation at tilt angles of 27 º to 33 º; and (ii) interdigitated monolayer intercalation of the C14 single alkyl chain surfactant and bilayer intercalation of the C16 double alkyl chains and its 1:1 mixture with the single chain surfactant. However, FTIR analysis revealed disordered alkyl chain conformations. White oil dispersions containing 10 mass % organo-bentonite (inorganic basis) featured high viscosities. They showed strong shear thinning behaviour confirming the ability of the montmorillonite particles to exfoliate.
Technology selection to produce alkylate from straight run Fischer−Tropsch syncrude has been investigated. Alkylate is a high octane paraffinic motor-gasoline component and can be produced by direct alkylation (olefin addition to isobutane) or indirect alkylation (isobutene dimerization followed by hydrogenation). Neither isobutane nor isobutene is abundant in the light fraction of Fischer−Tropsch syncrude, which is rich in linear alpha-olefins. Direct alkylation (HF and H2SO4) and indirect alkylation (acidic resin and solid phosphoric acid) based flowschemes were evaluated in terms of alkylate yield, octane number, compatibility to Fischer−Tropsch derived feed, and environmental friendliness. It was found that the refining focus determined the selection. Indirect alkylation with solid phosphoric acid was found to be the best in terms of Fischer−Tropsch feed compatibility, environmental friendliness, and least refining complexity. The highest alkylate yield could be obtained by a combination of partial olefin hydrogenation, hydroisomerization, and direct alkylation. Butene skeletal isomerization in combination with indirect alkylation yielded an alkylate with the highest octane number.
Using MV overshoot as a tuning metric in choosing DMC move suppression values. AbstractTraditionally the tuning of dynamic matrix control (DMC) type multivariable controllers is done by trial and error. The APC engineer chooses arbitrary starting values and tests the performance on a simulated controller. The engineer then either increases the values to suppress movement more, or decreases them to have the manipulated variables move faster. When the controller performs acceptably in simulation, then the tuning is improved during the commissioning of the controller on the plant. This is a time consuming and unscientific exercise and therefore often does not get the required attention. This leads to unacceptable controller behaviour during commissioning and sub-optimal control once commissioning is completed. This paper presents a new method to obtain move suppression factors for DMC type multivariable controllers by using a Nelder Mead search algorithm to find move suppressions that will provide acceptable control behaviour. Acceptable behaviour is described by characterising the dynamic move plan calculated by the controller for each of the manipulated variables.
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