Thermal
insulating fibers can effectively regulate the human body
temperature and decrease indoor energy consumption. However, designing
super thermal insulating fibers integrating a sponge and aerogel structure
based on biomass resources is still a challenge. Herein, a flow-assisted
dynamic dual-cross-linking strategy is developed to realize the steady
fabrication of regenerated all-cellulose graded sponge–aerogel
fibers (CGFs) in a microfluidic chip. The chemically cross-linked
cellulose solution is used as the core flow, which is passed through
two sheath flow channels, containing either a diffusion solvent or
a physical cross-linking solvent, resulting in CGFs with a porous
sponge outer layer and a dense aerogel inner layer. By regulating
and simulating the flow process in the microfluidic chip, CGFs with
adjustable sponge thicknesses, excellent toughness (26.20 MJ m–3), and ultralow thermal conductivity (0.023 W m–1 K–1) are fabricated. This work
provides a new method for fabricating graded biomass fibers and inspires
attractive applications for thermal insulation in textiles.
Nanocomposites from native cellulose with low 2D nanoplatelet content are of interest as sustainable materials combining functional and structural performance. Cellulose nanofibril-graphene oxide (CNF-GO) nanocomposite films are prepared by a...
Transparent wood
biocomposites based on PMMA combine high optical
transmittance with excellent mechanical properties. One hypothesis
is that despite poor miscibility the polymer is distributed at the
nanoscale inside the cell wall. Small-angle neutron scattering (SANS)
experiments are performed to test this hypothesis, using biocomposites
based on deuterated PMMA and “contrast-matched” PMMA.
The wood cell wall nanostructure soaked in heavy water is quantified
in terms of the correlation distance
d
between the
center of elementary cellulose fibrils. For wood/deuterated PMMA,
this distance
d
is very similar as for wood/heavy
water (correlation peaks at
q
≈ 0.1 Å
–1
). The peak disappears when contrast-matched PMMA
is used, indeed proving nanoscale polymer distribution in the cell
wall. The specific processing method used for transparent wood explains
the nanocomposite nature of the wood cell wall and can serve as a
nanotechnology for cell wall impregnation of polymers in large wood
biocomposite structures.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.