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Abstract:In this study, zinc oxide nanoparticles (ZnO NPs) in powder and in thin film were successfully synthesized first time using an eco-friendly, simple and cost effective green synthesis method mediated by corn husk (Zea mays) extract as an effective chelating agent, and zinc nitrate hexahydrate as precursor. Diverse characterizations techniques such as High Resolution – Scanning Electron Microscopy (HR-SEM), Energy Dispersive X- rays Spectroscopy (EDS), X-Rays Diffraction (XRD), and UV – Vis – NIR spectroscopy as well as Photoluminescence (PL) were investigated to confirm ZnO NPs nature. For the ZnO NPs powder, highly crystalline ZnO nanoparticles (ZnO NPs) annealed at 500°C which are 48.635 nm in particles size were characterised by HR-SEM and XRD analysis. The structure morphology and the constituents of the resultant ZnO powder were investigated respectively by HR-SEM and EDS. UV – Visible spectroscopy analysis was investigated on the optical band gap of ZnO NPs, which was calculated to be 3.31 eV. This result indicates that ZnO NPs can be used in metal oxide semiconductor-based devices. For the ZnO NPs thin film, XRD patterns of hexagonal wurtzite structure with c/a ratio about of 1.60 and μ – parameter of 0.38 were obtained. PL measurements showed a broad emission band in the 380 – 800 nm range, centred at 481 nm. ZnO NPs thin film yielded relatively more intense photoluminescence spectra than the ZnO NPs powder. The intrinsic point defects and defect level transitions responsible for the broad emission are discussed.

The work we present in this paper is a continuation of a series of studies on the numerical study of natural convection in a square porous cavity saturated by a Newtonian fluid. The left vertical wall is subjected to a temperature varying sinusoidally in time while the right vertical wall is either at a constant temperature, or varying sinusoidally in time. The upper and lower horizontal walls are thermally adiabatic. Darcy model is used, it is also assumed the fluid studied is incompressible and obeys the Boussinesq approximation. The focus is on the effect of the modulation frequency ( 10 100 ω ≤ ≤ ) on the structure of the flow and transfer thermal. The results show that the extremal stream functions ( max ψ et min ψ ), the average Nusselt number at the hot ( h T ) and cold ( c T ) walls respectively Nuh and Nuc are periodic in the range of parameters considered in this study. In comparison with the constant heating conditions, it is found that the variable heating causes the appearance of secondary flow, whose amplification depends on the frequency of modulation of the imposed temperature but also of the heating mode. The results are shown in terms of streamlines and isotherms during a flow cycle.

Combinatorial experiments provide a means of generating large amounts of experimental data; however that does not necessarily lead to high throughput interpretation of that data. In this paper we provide a brief summary of how one can use informatics techniques to accelerate data interpretation from high throughput experiments. We provide examples from high throughput nanoindentation and diffraction experiments.

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