A new technique,`topo-tomography', suitable for the characterization of the three-dimensional defect structure in bulk crystals, is proposed. The technique consists of the combination of diffraction topography and microtomography. It is applicable to high-quality single crystals, provided that the`direct image' is the dominant contrast mechanism. In this case, crystal defects give rise to locally enhanced intensity compared with the perfect-crystal matrix. The additional intensities sum along the diffracted-beam direction and yield projections of the local Bragg re¯ectivity. Like in the case of absorption tomography, the threedimensional distribution of this re¯ectivity can be reconstructed from a large number of projections. The ®rst experimental results of this technique, applied to a synthetic diamond crystal, are presented.

Crystals are the elementary constituents of Laue lenses, an emerging technology which could allow the realization of a space‐borne telescope 10–100 times more sensitive than existing ones, in the 100 keV–1.5 MeV energy range. This paper addresses the development of efficient crystals for the realization of a Laue lens. In the theoretical part, 35 candidate crystals, both pure and two‐component crystals, are considered. Their peak reflectivity at 100, 500 keV and 1 MeV is calculated assuming they are mosaic crystals. It is found that, by careful selection of crystals, it is possible to achieve a reflectivity above 30% over the whole energy range, and even up to 40% in the lower part of the energy range. In the experimental part, three different materials (Si1−xGex with a gradient of composition, mosaic Cu and Au) have been measured at both ESRF and ILL using highly monochromatic beams ranging from 300 to 816 keV. The aim was to check their homogeneity, quality and angular spread (mosaicity). These crystals have shown outstanding performance, such as reflectivity up to 31% at ∼600 keV (Au) or 60% at 300 keV (SiGe) and angular spread as low as 15 arcsec for Cu, fulfilling very well the requirements for a Laue lens application. An unexpected finding is that there are important discrepancies with Darwin's model when a crystal is measured using various energies.

Quasicrystals are long-range-ordered materials that lack translational invariance, so the study of their physical properties remains a challenging problem. Here, we have carried out inelastic-X-ray- and neutron-scattering experiments on single-grain samples of the Zn-Mg-Sc icosahedral quasicrystal and of the Zn-Sc periodic cubic 1/1 approximant, with the aim of studying the respective influence of the local order and of the long-range order (periodic or quasiperiodic) on lattice dynamics. Besides the overall similarities and the existence of a pseudo-gap in the transverse dispersion relation, marked differences are observed, the pseudo-gap being larger and better defined in the approximant than in the quasicrystal. This can be qualitatively explained using the concept of a pseudo-Brillouin-zone in the quasicrystal. These results are compared with simulations on atomic models and using oscillating pair potentials, and the simulations reproduce in detail the experimental results. This paves the way for a detailed understanding of the physics of quasicrystals.

International audienceIce single crystals were deformed under torsion and dislocation arrangements were analyzed by synchrotron topography at ESRF (European Synchrotron Radiation Facility). Profile analysis of the topographs revealed the scale-invariant character of the dislocation arrangement with long-range correlations. Dislocation density gradients are shown to be slightly anti-correlated as the intensity profile is similar to an anti-persistent random walk-like signal. This analysis reveals the influence of internal stresses on dislocation arrangement up to the sample scale. Similar observations in reversed torsion experiments, together with strong hardening behaviour, allow a mechanism of cross-slip of basal dislocations on prismatic planes to be suggested for interpretation of local dislocation interaction behaviour