Several modified terpolymer polyketones (MPK) with N-substituted pyrrole moieties in the main chain and quaternized amine in the side group were synthesized for use as anion exchange membranes for fuel cells. The moieties were carried by SiO2 nanoparticles through surface functionalization (Si–N), which were added to the membranes to enhance their overall properties. On increasing the amount of modified silica from 10% to 60% wt/of MPK, there was an increase in Si–N and a corresponding threefold increase in the hydroxide conductivity of the membrane. The MPK–SiN (60%) exhibited a superior ionic conductivity of 1.05 × 10−1 S.cm−1 at 120 °C, a high mechanical stability, with a tensile strength of 46 MPa at 80 °C. In strongly alkaline conditions (1 M KOH, 216 h at 80 °C), the membranes maintained about 70% of the conductivity measured in a usual environment. Fuel cell performance at 80 °C showed a peak power density of 133 mW·cm−2, indicating that using surface-functionalized SiO2 is a simple and effective way to enhance the overall performance of anion exchange membranes in fuel cell applications.
Air permeability measurements according to the Hagen–Poiseuille equation, Scanning Electron Microscopy (SEM) and mercury intrusion porosimetry (MIP) tests were conducted on samples of cementitious mortar at different curing times to study the correlation between the increased crystallization and their microstructure. The mortar samples were prepared with a commercial fast-setting premix containing calcium silicates and quartz. The average permeability coefficient (K) was 2.96 × 10−15 m2 after 3 days and decreased to 3.07 × 10−17 m2 after about one month. The continuous C-S-H nucleation in the capillary pores of the cement mortar changes their shape and improves the mortar’s impermeability. The SEM images showed the development of crystals that refine the pore size distribution of the cement paste, with more of the smallest pores, and fewer of the largest, as demonstrated by the MIP measurements. Adding a superabsorbent polyacrylate (SA-PA) in the amount of 0.5% wt of dry powder, without adding any extra water, makes a mortar less fluid but not faster-setting. Twenty-four hours after mixing and casting, it is still plastic and, with time, the pore size distribution differs from that of standard mortar. Over time in air, permeability remains high, but in water it could be low due to swelling of SA-PA residues.
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