We present a series of experiments, using different techniques such as light scattering, conoscopy, neutron scattering and microscopic observations, to determine the orientation of lyotropic lamellar phases under shear. Three states of orientation are observed, depending upon both the shear rate and the inter-membrane separation. These steady states are separated by dynamic transitions. Among the states described, we focus our attention on a state made of monodisperse close-packed multilayered vesicles whose size is precisely fixed by the shear rate
Small-angle X-ray and neutron-scattering techniques have been used to probe the structure of swollen Nafion membranes in the range 10-10000 Å. From analyzing the scattering data as a function of the polymer volume fraction and using a contrast variation method for the neutron experiments, we suggest a new structural model of Nafion in the hydrated state. It is based on the aggregation of the ionomer chains into elongated polymeric bundles with a diameter on the order of 40 Å and a length larger than 1000 Å, surrounded by the electrolyte solution.
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