In this work, we investigated structural, morphological, electrical, and optical properties from a set of Cu 2 ZnSnS 4 thin films grown by sulfurization of metallic precursors deposited on soda lime glass substrates coated with or without molybdenum. X-ray diffraction and Raman spectroscopy measurements revealed the formation of single-phase Cu 2 ZnSnS 4 thin films. A good crystallinity and grain compactness of the film was found by scanning electron microscopy. The grown films are poor in copper and rich in zinc, which is a composition close to that of the Cu 2 ZnSnS 4 solar cells with best reported efficiency. Electrical conductivity and Hall effect measurements showed a high doping level and a strong compensation. The temperature dependence of the free hole concentration showed that the films are nondegenerate. Photoluminescence spectroscopy showed an asymmetric broadband emission. The experimental behavior with increasing excitation power or temperature cannot be explained by donor-acceptor pair transitions. A model of radiative recombination of an electron with a hole bound to an acceptor level, broadened by potential fluctuations of the valence-band edge, was proposed. An ionization energy for the acceptor level in the range 29-40 meV was estimated, and a value of 172 ± 2 meV was obtained for the potential fluctuation in the valence-band edge.

We studied the solid-phase reaction between a thin Ni film and a single crystal Ge(001) or Ge(111) substrate during a ramp anneal. The phase formation sequence was determined using in situ X-ray diffraction and in situ Rutherford backscattering spectrometry (RBS), while the nature and the texture of the phases were studied using X-ray pole figures and transmission electron microscopy. The phase sequence is characterized by the formation of a single transient phase before NiGe forms as the final and stable phase. X-ray pole figures were used to unambiguously identify the transient phase as the-phase, a non-stoichiometric Ni-rich germanide with a hexagonal crystal structure that can exist for Ge concentrations between 34% and 48% and which forms with a different epitaxial texture on both substrate orientations. The complementary information gained from both RBS and X-ray pole figure measurements revealed a simultaneous growth of both the-phase and NiGe over a small temperature window on both substrate orientations. V

Cu 2 ZnSnS 4 is a promising semiconductor to be used as absorber in thin film solar cells. In this work, we investigated optical and structural properties of Cu 2 ZnSnS 4 thin films grown by sulphurization of metallic precursors deposited on soda lime glass substrates. The crystalline phases were studied by X-ray diffraction measurements showing the presence of only the Cu 2 ZnSnS 4 phase. The studied films were copper poor and zinc rich as shown by inductively coupled plasma mass spectroscopy. Scanning electron microscopy revealed a good crystallinity and compactness. An absorption coefficient varying between 3 and 4 × 10 4 cm −1 was measured in the energy range between 1.75 and 3.5 eV. The bad gap energy was estimated in 1.51 eV. Photoluminescence spectroscopy showed an asymmetric broad band emission. The dependence of this emission on the excitation power and temperature was investigated and compared to the predictions of the donor-acceptor-type transitions and radiative recombinations in the model of potential fluctuations. Experimental evidence was found to ascribe the observed emission to radiative transitions involving tail states created by potential fluctuations.

Recent studies have made key progress on the black hole/solitonic solutions of the Einstein-Proca system. Firstly, fully non-linear dynamical evolutions of the Kerr black hole superradiant instability, triggered by a Proca field, have shown the formation of a new equilibrium state, a spinning black hole with synchronised Proca hair. Secondly, non-linear evolutions of spinning Proca stars have established that they are dynamically stable, unlike their scalar cousins. Thirdly, separability of the Proca equation on the Kerr background has been achieved. Motivated by these results, in this paper we reconsider Kerr black holes with synchronised Proca hair. The separability of the Proca equation on the Kerr background allows us to examine the stationary Proca clouds in greater detail, in particular their dependence on the different quantum numbers. These stationary clouds occur at a set of existence lines in the Kerr parameter space, from which the black holes with synchronised Proca hair bifurcate. We construct the domain of existence of these black holes, comparing the fundamental states missed in the original study with the first excited states and with the cousin scalar model, giving illustrative examples of Kerr-like and non- Kerr-like BHs. In the vanishing event horizon limit, these hairy black holes connect to the fundamental states of spinning Proca stars, which include the dynamically stable solutions.