Understanding optimal process conditions is an essential step in providing high-quality fuel for energy production, efficient energy generation, and plant development. Thus, the effect of process conditions such as the temperature, time, nitrogen-to-solid ratio (NSR), and liquid-to-solid ratio (LSR) on pretreated waste pine sawdust (PSD) via torrefaction and solvolysis is presented. The desirability function approach and genetic algorithm (GA) were used to optimize the processes. The response surface methodology (RSM) based on Box–Behnken design (BBD) was used to determine the effect of the process conditions mentioned above on the higher heating value (HHV), mass yield (MY), and energy enhancement factor (EEF) of biochar/hydrochar obtained from waste PSD. Seventeen experiments were designed each for torrefaction and solvolysis processes. The benchmarked process conditions were as follows: temperature, 200–300 °C; time, 30–120 min; NSR/LSR, 4–5. In this study, the operating temperature was the most influential variable that affected the pretreated fuel’s properties, with the NSR and LSR having the least effect. The oxygen-to-carbon content ratio and the HHV of the pretreated fuel sample were compared between the two pretreatment methods investigated. Solvolysis pretreatment showed a higher reduction in the oxygen-to-carbon content ratio of 47%, while 44% reduction was accounted for the torrefaction process. A higher mass loss and energy content were also obtained from solvolysis than the torrefaction process. From the optimization process results, the accuracy of the optimal process conditions was higher for GA (299 °C, 30.07 min, and 4.12 NSR for torrefaction and 295.10 °C, 50.85 min, and 4.55 LSR for solvolysis) than that of the desirability function based on RSM. The models developed were reliable for evaluating the operating process conditions of the methods studied.

The impacts of fossil energy on the climate and environment emphasize the need for alternative energy resources. The use of waste wood is one such method to potentially reduce fossil-based energy dependence. However, raw biomass fuel properties are generally poor and unpredictable, thus requiring pretreatment to maximize their energy potentials for an efficient conversion to syngas via pyro-gasification. Two species of pine sawdust (PSD) wastes generated in abundance from large-scale timber industries in Nigeria and South Africa were investigated for improvements in their fuel properties after torrefaction. Samples were torrefied under optimum conditions of 300 °C and 45 min. Different analytical procedures show that the higher heating value (HHV), enhancement factor, energy density, and solid yield of the Nigerian PSD exceeded those of their South African counterpart by 2.38, 5.37, 3.49, and 11.15%, respectively. The HHV of the torrefied fuels increased by 57.29 and 37.9% for the Nigerian and South African PSDs, respectively, when compared to the raw fuels. Also investigated were improvements in their H/C and O/C ratios and thermal degradation at varied heating rates.

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INTRODUCTION: Despite several studies carried out on the effects of the fuel properties of raw biomass on the final fuel properties of the biofuel after a thermochemical conversion, an identification and grading of various biomass types with respect to the level of their viability for pyro-gasification has not been established. OBJECTIVES: The primary objective of this study was to identify and rank eight waste wood feedstocks based on the suitability of their fuel properties for an efficient pyro-gasification using experimental data. METHODS: The wood samples were characterized using standard experimental procedures to determine their fuel properties. Five fuel evaluators relevant to the efficiency of a pyrogasification process, were developed. The experimental data collated for each sample was used to carry out an evaluation exercise of the samples under each of the five fuel evaluators. Finally, the result of this exercise was used to rank the wood samples based on their suitability as feedstock for pyro-gasification. RESULTS: The hardwoods such as the Eucalyptus and African mesquite exhibited high fuel ratios, heating value and energy density which was as result of their higher lignin content. However, they exhibited minimal char reactivity. Conversely due to its higher holocellulose-to-lignin ratio, the Bugweed exhibited high char reactivity but lower fuel ratio, heating value and energy density. In comparison to the literature, the experimental results in this study were somewhat consistent with those of other biomass samples previously reported. The Fuel characterization exercise reveals that no wood sample can be considered completely efficient for pyro-gasification. The Jacaranda was however ranked lowest across the board. CONCLUSION: The variations in the hierarchy of the samples under the different fuel evaluators due to the disparities in their fuel properties paves way for further studies on the blending of waste wood samples with contrasting fuel properties in different mix ratios. This would enable the production of feedstock with the right balance in fuel properties suitable for an efficient pyro-gasification process. This study provides stakeholders with a framework for blending different lignocellulosic biomass species for thermochemical conversion.