Six new uranyl hybrid materials have been synthesized solvothermally utilizing the ligands 2,2′-bipyridine-3,3′-dicarboxylic acid (H 2 L) and 2,2′:6′,2′′-terpyridine (TPY). The six compounds are classified as either molecular complexes ( 6). A discussion of the influence of transition metal incorporation, chelating effects of the ligand, and synthesis conditions on the formation of uranyl materials is presented. The structure of compound 6 is of particular note due to large channel-like voids with a diameter of approximately 19.6 Å.
Herein we report on the synthesis of (C4H6N)2[UO2Cl3(H2O)(Pyz)0.5]2.2H2O which features a novel pyrazine-bridged uranyl dimer, [UO2Cl3(H2O)(Pyz)0.5]22-. A rigorous computational and experimental analysis of this compound was performed to fully explore...
We report the synthesis and characterization of a family of UO22+/Co2+ isothiocyanate materials containing [UO2(NCS)5]3- and/or [Co(NCS)4]2- building units charged balanced by tetramethylammonium cations and assembled via S…S or S…Oyl...
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