Natural rubber (NR) nanocomposites have been prepared with hydroxylated barium titanate filler (BaTiO3-OH), employing emulsion polymerization followed by vulcanization process. The addition of barium titanate, a compound with high dielectric permittivity, was envisaged to increase the insulating properties of NR films, thereby reducing the electrical stress and the possibility of undesired arcing on their surfaces. The content of perovskite particles greatly affected both, the mechanical and the electrical properties, of the vulcanized films. It was observed that the optimum functionalized nanoparticle concentration is around 0.25-0.50 phr, range in which the elongation of break was maintained between 874-935 % and the tensile strength was between 4.40-4.80 MPa; whereas the dielectric permittivity (ε') is slightly lower than the pristine NR or the NR compounded with high content of BaTiO3 nanoparticles. The dielectric study revealed the presence of two dielectric relaxation modes: (i) glass to rubber transition (α-relaxation) and (ii) interfacial polarization (IP), known as Maxwell−Wagner−Sillars (MWS) polarization. The comparison between small concentrations of non-functionalized and functionalized BaTiO3 inside NR polymeric films lead to the conclusion that the dielectric breakdown strength is high for non-functionalized fillers, supposedly due to less IP polarization phenomena.
Recent studies on London Clay have identified a number of different units in the geological profile, and have highlighted the role of soil structure in mechanical behaviour. In fact, structure is the dominant factor determining the differences in the mechanical response of different units. In the paper, numerical analyses simulating the undrained excavation of a tunnel in St James's Park are presented. London Clay behaviour is characterised by a kinematic-hardening structured soil model incorporating structure and stiffness degradation. The parameters and initial conditions are based on a careful calibration that takes into account the presence of different units within the London Clay formation and the different degrees of soil structure. The analyses performed result in a very satisfactory reproduction of the magnitude and patterns of short-term surface and subsurface displacements, as well as pore pressures. The paper concludes with a discussion of the results in the context of other analyses performed previously, and puts forward some considerations concerning design issues.
Using realistic constitutive models for artificially cemented soils is advantageous in design. However, the price of that increased realism is often a more elaborate model, which is difficult to calibrate. A database of high quality triaxial tests on compacted cemented silty sand is used to calibrate and validate a generalized critical state bonded soil model. The exercise highlights the staged calibration procedure that is convenient in this kind of application. The calibration results have shown a direct relation between added yield strength and a well-established soil-cement mixture ratio, which facilitates the application of the model in design. It is shown that such relation can be also deduced from the analysis of unconfined compressive strength tests.
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