The saturated hydrocarbons ethane (C2H6) and methane (CH4) along with carbon monoxide (CO) and water (H2O) were detected in comet C/1996 B2 Hyakutake with the use of high-resolution infrared spectroscopy at the NASA Infrared Telescope Facility on Mauna Kea, Hawaii. The inferred production rates of molecular gases from the icy, cometary nucleus (in molecules per second) are 6.4 X 10(26) for C2H6, 1.2 X 10(27) for CH4, 9.8 X 10(27) for CO, and 1.7 X 10(29) for H2O. An abundance of C2H6 comparable to that of CH4 implies that ices in C/1996 B2 Hyakutake did not originate in a thermochemically equilibrated region of the solar nebula. The abundances are consistent with a kinetically controlled production process, but production of C2H6 by gas-phase ion molecule reactions in the natal cloud core is energetically forbidden. The high C2H6/CH4 ratio is consistent with production of C2H6 in icy grain mantles in the natal cloud, either by photolysis of CH4-rich ice or by hydrogen-addition reactions to acetylene condensed from the gas phase.

We present a comparison of CO fundamental rovibrational lines (observed in the M band near 4.7 lm) from the inner circumstellar disks around the Herbig AeBe stars AB Aur and HD 141569. The CO spatial profiles and temperatures constrain the location of the gas for both stars to a distance of less than 50 AU. The CO emission from the disk of the $4 Myr star AB Aur shows at least two temperature components, the inner disk at a rotational temperature of 1540 AE 80 K and the outer disk at 70 AE 10 K. The hot gas is located near the hot bright inner rim of the disk and the cold gas is located in the outer disk from 8-50 AU. The relative intensities of low-J lines suggest that the cold gas is optically thick. The excitation of CO in both temperature regimes is dominated by infrared fluorescence (resonant scattering). In the more evolved disk around HD 141569, the CO is excited by UV fluorescence. The relative intensity of the CO emission lines implies a rotational temperature of 190 AE 30 K. The resulting column density is $10 11 cm À2 , indicating approximately 10 19 g of CO. The observed line profiles indicate that the inner disk has been cleared of CO gas by stellar radiation out to a minimum of 17 AU. The residual mass of CO suggests that the inner disk of HD 141569 is not in an active phase of planet building but it does not rule out the possibility that giant planet building has previously occurred.

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