Aryltrimethylstannanes react with aldehydes in the presence of a catalytic amount of a cationic rhodium complex, [Rh(cod)(MeCN) 2 ]BF 4 , affording the corresponding arylated secondary alcohols in good yields.
Aryltrimethylstannanes react with α,β-unsaturated ketones and esters in the presence of a catalytic amount of a cationic rhodium complex, [Rh(cod)(MeCN)2]BF4, affording the conjugate addition products in good yields.
lytic amount of a cationic rhodium complex, [Rh(cod)-(CH 3 CN) 2 ]BF 4 , affording the corresponding phenylated alcohols in good yield. The reaction mechanism involves the transmetalation between a fluorine-coordinated silicate and a rhodium complex to generate a phenylrhodium species.
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