The beautiful structural colors in bird feathers are some of the brightest colors in nature, and some of these colors are created by arrays of melanin granules that act as both structural colors and scattering absorbers. Inspired by the color of bird feathers, high-visibility structural colors have been created by altering four variables: size, blackness, refractive index, and arrangement of the nano-elements. To control these four variables, we developed a facile method for the preparation of biomimetic core-shell particles with melanin-like polydopamine (PDA) shell layers. The size of the core-shell particles was controlled by adjusting the core polystyrene (PSt) particles’ diameter and the PDA shell thicknesses. The blackness and refractive index of the colloidal particles could be adjusted by controlling the thickness of the PDA shell. The arrangement of the particles was controlled by adjusting the surface roughness of the core-shell particles. This method enabled the production of both iridescent and non-iridescent structural colors from only one component. This simple and novel process of using core-shell particles containing PDA shell layers can be used in basic research on structural colors in nature and their practical applications.

A novel approach for creating non-iridescent bright structural color materials from polydopamine (PDA) black particles that mimic melanin granules found in nature is presented. 43 290 3393; Tel: +81 43 290 3393 † Electronic supplementary information (ESI) available. See

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Polydopamine (PDA) is of interest as a mimetic material of melanin to produce structural color materials. Herein, to investigate the influence of the material composition of the artificial melanin particles on structural color, we demonstrated the preparation of core-shell particles by polymerization of norepinephrine or 3,4-dihydroxyphenylalanine, which are melanin precursors similar to dopamine, in the presence of polystyrene particles. It was revealed that the arrays of the prepared particles produce high-visibility structural color because of absorption of scattering light. Although poly(3,4-dihydroxyphenylalanine) showed the same tendency as PDA which was previous studied, polynorepinephrine can easily produce a smooth and thick shell layer compared with that of PDA, and pellets consisting of the particles showed angle-dependent structural color. Therefore, the artificial melanin particles that produce angle-dependent structural color became stable than ever before. These results indicated that material compositions of artificial melanin particles have influence on structural color, and an important finding for application as a coloring material was obtained.