Abstract. Although precipitation has been measured for many centuries, precipitation measurements are still beset with significant inaccuracies. Solid precipitation is particularly difficult to measure accurately, and wintertime precipitation measurement biases between different observing networks or different regions can exceed 100 %. Using precipitation gauge results from the World Meteorological Organization Solid Precipitation Intercomparison Experiment (WMO-SPICE), errors in precipitation measurement caused by gauge uncertainty, spatial variability in precipitation, hydrometeor type, crystal habit, and wind were quantified. The methods used to calculate gauge catch efficiency and correct known biases are described. Adjustments, in the form of "transfer functions" that describe catch efficiency as a function of air temperature and wind speed, were derived using measurements from eight separate WMO-SPICE sites for both unshielded and single-Alter-shielded precipitationweighing gauges. For the unshielded gauges, the average undercatch for all eight sites was 0.50 mm h −1 (34 %), and for the single-Alter-shielded gauges it was 0.35 mm h −1 (24 %). After adjustment, the mean bias for both the unshielded and single-Alter measurements was within 0.03 mm h −1 (2 %) of zero. The use of multiple sites to derive such adjustments makes these results unique and more broadly applicable to other sites with various climatic conditions. In addition, errors associated with the use of a single transfer function to correct gauge undercatch at multiple sites were estimated.

Complex refractive indices of supercooled liquid water at 240, 253, 263, and 273 K, and ice at 200, 210, and 235 K in the mid infrared from 460 to 4000 cm(-1) are reported. The results were obtained from the extinction spectra of small (micron-size) aerosol particles, recorded using the cryogenic flow tube technique. An improved iterative procedure for retrieving complex refractive indices from extinction measurements is described. The refractive indices of ice determined in the present study are in good agreement with data reported earlier. The temperature region and range of states covered in the present work are relevant to the study of upper tropospheric and stratospheric aerosols and clouds.

[1] Cloud and aerosol data acquired by the National Research Council of Canada (NRC) Convair-580 aircraft in, above, and below single-layer arctic stratocumulus cloud during the Indirect and Semi-Direct Aerosol Campaign (ISDAC) in April 2008 were used to test three aerosol indirect effects hypothesized to act in mixed-phase clouds: the riming indirect effect, the glaciation indirect effect, and the thermodynamic indirect effect. The data showed a correlation of R = 0.78 between liquid drop number concentration, N liq inside cloud and ambient aerosol number concentration N PCASP below cloud. This, combined with increasing liquid water content LWC with height above cloud base and the nearly constant vertical profile of N liq , suggested that liquid drops nucleated from aerosol at cloud base. No evidence of a riming indirect effect was observed, but a strong correlation of R = 0.69 between ice crystal number concentration N i and N PCASP above cloud was noted. Increases in ice nuclei (IN) concentration with N PCASP above cloud for 2 flight dates combined with the subadiabatic LWC profiles suggest possible mixing of IN from cloud top consistent with the glaciation indirect effect. The lower N ice and lower effective radius r el for the more polluted ISDAC cases compared to data collected in cleaner single-layer stratocumulus conditions during the Mixed-Phase Arctic Cloud Experiment is consistent with the operation of the thermodynamic indirect effect. However, more data in a wider variety of meteorological and surface conditions, with greater variations in aerosol forcing, are required to identify the dominant aerosol forcing mechanisms in mixed-phase arctic clouds.

Abstract. Temperature-dependent volume nucleation rate coefficients for supercooled water droplets, J V (T ), are derived from infrared extinction measurements in a cryogenic laminar aerosol flow tube using a microphysical model. The model inverts water and ice aerosol size distributions retrieved from experimental extinction spectra by considering the evolution of a measured initial droplet distribution via homogeneous nucleation and the exchange of vapour-phase water along a well-defined temperature profile. Experiment and model results are reported for supercooled water droplets with mean radii of 1.0, 1.7, and 2.9 µm. Values of mass accommodation coefficients for evaporation of water droplets and vapour deposition on ice particles are also determined from the model simulations. The coefficient for ice deposition was found to be 0.031 ± 0.001, while that for water evaporation was 0.054 ± 0.012. Results are considered in terms of the applicability of classical nucleation theory to the freezing of micrometre-sized droplets in cirrus clouds, with implications for the parameterization of homogeneous ice nucleation in numerical models.