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In this paper, the effects of Dufour and thermal diffusion and on unsteady MHD (magnetohydrodynamic) free convection and mass transfer flow through an infinite vertical permeable sheet have been investigated numerically. The non-dimensional governing equations are solved numerically by using the superposition method with the help of “Tec plot” software. The numerical solution regarding the non-dimensional velocity, temperature, and concentration variables against the non-dimensional coordinate variable has been carried out for various values of pertinent numbers and parameters like the suction parameter $$\left( {v_{0} } \right)$$ v 0 , Prandtl number $$\left( {P_{r} } \right)$$ P r , magnetic parameter $$\left( M \right)$$ M , Dufour number $$\left( {D_{f} } \right)$$ D f , Soret number $$\left( {S_{0} } \right)$$ S 0 , Schmidt number $$\left( {S_{c} } \right)$$ S c , and for constant values of modified local Grashof number $$\left( {G_{{\text{m}}} } \right)$$ G m and local Grashof number $$\left( {G_{r} } \right)$$ G r .The velocity field decreases for increasing the suction parameter which is focusing on the common fact that the usual suction parameter stabilizing the effect on the boundary layer growth. The thermal boundary layer thickness becomes thinner for rising values of the Dufour and Soret numbers. The skin friction enhances for uplifting values of Soret number and Dufour number but reduces for moving suction parameter, Magnetic force number, Prandtl number, and Schmidt number. The heat transfer rate increases for increasing the suction parameter, Dufour number, Prandtl number, and Soret number. The mass transfer rate increases for enhancing the values of suction parameter, Magnetic force number, Soret number, and Prandtl number but decreases for Dufour number and Schmidt number.

Radiation is an important branch of thermal engineering which includes geophysical thermal insulation, ground water pollution, food processing, cooling of electronic components, oil recovery processes etc. An analysis of unsteady magneto-convective heat-mass transport by micropolar binary mixture of fluid passing a continuous permeable surface with thermal radiation effect has been introduced in this paper. The governing equations are transformed into coupled ordinary differential equations along with Boussinesq approximation by imposing the similarity analysis. Applying the shooting technique, the obtained non-linear coupled similarity equations are solved numerically with the help of “ODE45 MATLAB” software. The results of the numerical solutions to the problem involving velocity, temperature, concentration and micro-rotation are presented graphically for different dimensionless parameters and numbers encountered. With an increase of suction parameter, the velocity distributions very closed to the inclined permeable wall decrease slightly where 0 ≤ η ≤ 0.3 . But for the uplifting values of sunction, both micro-rotation profile and species concentration enhance through the boundary layer. The skin-friction coefficient increases about 61%, 13%, 27% for rising values of Prandtl number (0.71-7), radiation effect (0 - 1) and thermal Grashof number (5-10), respectively, but an adverse effect is observed for magnetic field (1 - 4), inclined angle 0 0 − 60 0 and Schmidt number (0.22 - 0.75). Heat transfer and mass transfer reduce about 82%, 53%, respectively, in increasing of Pr (0.71-1) and 36%, 11%, respectively, in increasing of thermal radiation (0 - 1). The surface couple stress increases about 26%, 49%, 64% and 30% with the increasing values of magnetic field (1-4), inclination angle 0 0 − 60 0 , suction (0-1) and Schmidt number (0.22-0.75), respectively. Finally, the present study has been compared with the earlier published results. It is observed that the comparison bears a good agreement.

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