No abstract

[1] We present results of in situ measurements of charged nanoparticles, electrons, and positive ions obtained during a sounding rocket flight in October 2004 from Kiruna, Sweden, under nighttime conditions. The particle measurement reveals positive charge signatures in the altitude range between 80 and 90 km corresponding to peak charge number densities of $100 e/cm 3 at around 86 km. Aerodynamical analysis of the sampling efficiency of our instrument reveals that the particles must have been larger than 2 nm assuming spherical particles with a density of 3 g/cm 3 . The plasma environment of the observed particles is dominated by negative and positive ions, with only few free electrons. A calculation of the mean particle charge expected for particles in a plasma consisting of electrons and positive and negative ions shows that the presence of sufficiently heavy and numerous negative ions (i.e., m n > 300 amu and l ! 50) can explain the observed positive particle charge. Citation:

Abstract. An empirical model of the lower, nonauroral ionosphere is presented which is excm,,very oa•u on tausu wave v•wv,•s ...... data from ropkot qm•nclingq The. ve• limited number of available profiles provides an empirical correction to a simple theoretical model. This analytical correction, which can be of a very low mathematical order, is determined individually for each pressure surface. An inclusion of this model in tabulated form into the international reference ionosphere (IRI) is foreseen, and electron density profiles for the conditions required by the user can be obtained by interpolation.

Large-scale energy storage and the utilization of biomass as a sustainable carbon source are global challenges of this century. The reversible storage of hydrogen covalently bound in chemical compounds is a particularly promising energy storage technology. For this, compounds that can be sustainably synthesized and that permit high-weight% hydrogen storage would be highly desirable. Herein, we report that catalytically modified lignin, an indigestible, abundantly available and hitherto barely used biomass, can be harnessed to reversibly store hydrogen. A novel reusable bimetallic catalyst has been developed, which is able to hydrogenate and dehydrogenate N-heterocycles most efficiently. Furthermore, a particular N-heterocycle has been identified that can be synthesized catalytically in one step from the main lignin hydrogenolysis product and ammonia, and in which the new bimetallic catalyst allows multiple cycles of high-weight% hydrogen storage.

Abstract. We present in situ observations of meteoric smoke particles (MSP) obtained during three sounding rocket flights in December 2010 in the frame of the final campaign of the Norwegian-German ECOMA project (ECOMA = Existence and Charge state Of meteoric smoke particles in the Middle Atmosphere). The flights were conducted before, at the maximum activity, and after the decline of the Geminids which is one of the major meteor showers over the year. Measurements with the ECOMA particle detector yield both profiles of naturally charged particles (Faraday cup measurement) as well as profiles of photoelectrons emitted by the MSPs due to their irradiation by photons of a xenon-flash lamp. The column density of negatively charged MSPs decreased steadily from flight to flight which is in agreement with a corresponding decrease of the sporadic meteor flux recorded during the same period. This implies that the sporadic meteors are a major source of MSPs while the additional influx due to the shower meteors apparently did not play any significant role. Surprisingly, the profiles of photoelectrons are only partly compatible with this observation: while the photoelectron current profiles obtained during the first and third flight of the campaign showed a qualitatively similar behaviour as the MSP charge density data, the profile from the second flight (i.e., at the peak of the Geminids) shows much smaller photoelectron currents. This may tentatively be interpreted as a different MSP composition (and, hence, different photoelectric properties) during this second flight, but at this stage we are not in a position to conclude that there is a cause and effect relation between the Geminids and this observation. Finally, the ECOMA particle detector used during the first and third flight employed three instead of only one xenon flash lamp where each of the three lamps used for one flight had a different window material resulting in different cut off wavelengths for these three lamp types. Taking into account these data along with simple model estimates as well as rigorous quantum chemical calculations, it is argued that constraints on MSP sizes, work function and composition can be inferred. Comparing the measured data to a simple model of the photoelectron currents, we tentatively conclude that we observed MSPs in the 0.5-3 nm size range with generally increasing particle size with decreasing altitude. Notably, this size information can be obtained because different MSP particle sizes are expected to result in different work functions which is both supported by simple classical arguments as well as quantum chemical calculations. clusters, rather than metal silicates, are the major constituents of the smoke particles.