New particle formation in the Arctic atmosphere is an important source of aerosol particles. Understanding the processes of Arctic secondary aerosol formation is crucial due to their significant impact on cloud properties and therefore Arctic amplification. We observed the molecular formation of new particles from low‐volatility vapors at two Arctic sites with differing surroundings. In Svalbard, sulfuric acid (SA) and methane sulfonic acid (MSA) contribute to the formation of secondary aerosol and to some extent to cloud condensation nuclei (CCN). This occurs via ion‐induced nucleation of SA and NH3 and subsequent growth by mainly SA and MSA condensation during springtime and highly oxygenated organic molecules during summertime. By contrast, in an ice‐covered region around Villum, we observed new particle formation driven by iodic acid but its concentration was insufficient to grow nucleated particles to CCN sizes. Our results provide new insight about sources and precursors of Arctic secondary aerosol particles.

Reactive iodine plays a key role in determining the oxidation capacity, or cleansing capacity, of the atmosphere in addition to being implicated in the formation of new particles in the marine boundary layer. The postulation that heterogeneous cycling of reactive iodine on aerosols may significantly influence the lifetime of ozone in the troposphere not only remains poorly understood but also heretofore has never been observed or quantified in the field. Here, we report direct ambient observations of hypoiodous acid (HOI) and heterogeneous recycling of interhalogen product species (i.e., iodine monochloride [ICl] and iodine monobromide [IBr]) in a midlatitude coastal environment. Significant levels of ICl and IBr with mean daily maxima of 4.3 and 3.0 parts per trillion by volume (1-min average), respectively, have been observed throughout the campaign. We show that the heterogeneous reaction of HOI on marine aerosol and subsequent production of iodine interhalogens are much faster than previously thought. These results indicate that the fast formation of iodine interhalogens, together with their rapid photolysis, results in more efficient recycling of atomic iodine than currently considered in models. Photolysis of the observed ICl and IBr leads to a 32% increase in the daytime average of atomic iodine production rate, thereby enhancing the average daytime iodine-catalyzed ozone loss rate by 10 to 20%. Our findings provide direct field evidence that the autocatalytic mechanism of iodine release from marine aerosol is important in the atmosphere and can have significant impacts on atmospheric oxidation capacity.

Mapping of fast ice displacement and investigating sea ice rheological behavior is a major open topic in coastal ice engineering and sea ice modeling. This study presents first results on Sentinel-1 repeat-pass space borne synthetic aperture radar interferometry (InSAR) in the Gulf of Bothnia over the fast ice areas. An InSAR pair acquired in February 2015 with a temporal baseline of 12 days has been studied here in detail. According to our results, the surface of landfast ice in the study area was stable enough to preserve coherence over the 12-day baseline, while previous InSAR studies over the fast ice used much shorter temporal baselines. The advantage of longer temporal baseline is in separating the fast ice from drift ice and detecting long term trends in deformation maps. The interferogram showed displacement of fast ice on the order of 40 cm in the study area. Parts of the displacements were attributed to forces caused by sea level tilt, currents, and thermal expansion, but the main factor of the displacement seemed to be due to compression of the drift ice driven by southwest winds with high speed. Further interferometric phase and the coherence measurements over the fast ice are needed in the future for understanding sea ice mechanism and establishing sustainability of the presented InSAR approach for monitoring dynamics of the landfast ice with Sentinel-1 data.

Seasonal landfast sea ice stretches along most Arctic coastlines and serves as a platform for community travel and subsistence, industry operations, and as a habitat for marine mammals. Landfast ice can feature smooth ice and areas of m-scale roughness in the form of pressure ridges. Such ridges can significantly hamper trafficability, but if grounded can also serve to stabilize the shoreward ice. We investigate the use of synthetic aperture radar interferometry (InSAR) to assess the formation and movement of ridges in the landfast sea ice near Utqiaġvik, Alaska. The evaluation is based on the InSAR-derived surface elevation change between two TanDEM-X bistatic image pairs acquired during January 2012. We compare the results with backscatter intensity, coastal radar data, and SAR-derived ice drift and evaluate the utility of this approach and its relevance for evaluation of ridge properties, as well as landfast sea ice evolution, dynamics, and stability. Data Curation, M.M.; Writing-Original Draft Preparation, M.M.; Writing-Review & Editing