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Vulcano is an active NW–SE-elongated composite volcano located in the central Aeolian archipelago. Based on available radiometric ages and tephrochronology, the exposed volcanism started at c. 127 ka and spread through eight Eruptive Epochs separated by volcano-tectonic events and major quiescent stages. Various eruptive centres and two intersecting multi-stage calderas resulted from such evolution. Vulcano geological history displays several changes of eruption magnitude, eruption styles and composition of magmas through time. Vulcano rocks range from basalt to rhyolite and show variable alkali contents, roughly increasing during time. Magmas with low to intermediate SiO2 contents and high-K to shoshonite affinity prevail in the early Epochs 1–5 (c. 127–28 ka), whereas intermediate to high-SiO2 shoshonite and potassic alkaline products dominate the last three Epochs (<30 ka). This sharp increase in silicic products is related to the shallowing of the plumbing system and resulting major role of the differentiation processes in shallow-level reservoirs. Radiogenic isotope compositions are variable (87Sr/86Sr=0.70424–0.70587, 143Nd/144Nd=0.51254–0.51276, 206Pb/204Pb=19.305–19.759, 207Pb/204Pb=15.659–15.752, 208Pb/204Pb=39.208–39.559) as a result of both source heterogeneities and shallow-level interaction of magmas with continental crust. The compositional variations of mafic magmatism with time suggest that the source zone changed from a metasomatized, fertile, ocean island basalt- (OIB-) like mantle to a metasomatized depleted lithospheric mantle.DVD:The 10 000 scale geological map of Vulcano is included on the DVD in the printed book and can also be accessed online at http://www.geolsoc.org.uk/Memoir37-electronic. Also included is a full geochemical data set for Vulcano.

The Lipari volcanic complex, situated in the central Aeolian sector, was constructed between c. 267 ka and medieval ages by various lava flows, scoriaceous deposits, lava domes (coulees) and pyroclastic products related to hydromagmatic and strombolian activities. The eruptive history of Lipari is described by nine Epochs of activity interrupted by dormant periods, volcano-tectonic phases and episodes of terrace formation during the Last Interglacial. Several partially overlapping volcanic edifices were active through time, mostly under control of the NNW–SSE and north–south (minor east–west) regional tectonic trends. The latest eruptive events of M. Pilato and Rocche Rosse occurred from AD 776 to 1220. Lipari rocks range from calc-alkaline basaltic andesites to rhyolites, with silicic rocks dominating during the last 43 ka. There is a clear increase in K2O and incompatible elements with time, with distinct trends for mafic-intermediate and silicic rocks. Sr, Nd and Pb isotope ratios are highly variable. Petrographic and geochemical data suggest AFC (assimilation plus fractional crystallization) and mixing as the main magma evolution processes, with important effects of crustal anatexis, in the context of a polybaric feeding system.DVD:The 10 000 scale geological map of Lipari is included on the DVD in the printed book and can also be accessed online at http://www.geolsoc.org.uk/Memoir37-electronic. Also included is a full geochemical data set for Lipari.