A sound knowledge and understanding of the thermal stability of nanowires is a prerequisite for the reliable implementation of nanowire-based devices. We investigate the morphology of Au nanowires annealed isothermally at different temperatures. During the processes, triggered by heating, the wires undergo various configurational changes to finally break up into chains of nanospheres at much lower than bulk melting temperatures due to capillary or so-called Rayleigh instability. The role of three parameters, namely, wire diameter, temperature, and annealing time, on the final morphology is investigated. Both the average sphere diameter and the mean spacing between adjacent spheres are larger than the values predicted for materials with isotropic surface energy. Possible reasons are discussed in the paper.

Rayleigh instability of copper nanowires has been experimentally demonstrated. After annealing 30–50-nm-diam wires at temperatures between 400 and 600°C, different stages of the fragmentation process are observed by scanning electron microscopy. At 400°C, the wires start to fragment, forming shorter sections at 500°C, and finally decaying into a chain of nanospheres at 600°C. Average diameter and spacing of the spheres are in agreement with theoretical predictions. The Rayleigh instability applied to nanowires provides a structuring technique producing long chains of nanospheres, which should find interesting applications, for instance, by guiding light below the diffraction limit via coherent coupling of surface-plasmon polaritons.

The fabrication of three-dimensional assemblies consisting of large quantities of nanowires is of great technological importance for various applications including (electro-)catalysis, sensitive sensing, and improvement of electronic devices. Because the spatial distribution of the nanostructured material can strongly influence the properties, architectural design is required in order to use assembled nanowires to their full potential. In addition, special effort has to be dedicated to the development of efficient methods that allow precise control over structural parameters of the nanoscale building blocks as a means of tuning their characteristics. This paper reports the direct synthesis of highly ordered large-area nanowire networks by a method based on hard templates using electrodeposition within nanochannels of ion track-etched polymer membranes. Control over the complexity of the networks and the dimensions of the integrated nanostructures are achieved by a modified template fabrication. The networks possess high surface area and excellent transport properties, turning them into a promising electrocatalyst material as demonstrated by cyclic voltammetry studies on platinum nanowire networks catalyzing methanol oxidation. Our method opens up a new general route for interconnecting nanowires to stable macroscopic network structures of very high integration level that allow easy handling of nanowires while maintaining their connectivity.

With infrared spectroscopic microscopy using synchrotron light, the authors studied resonant light scattering from single metal nanowires with diameters in the 100nm range and with lengths of a few microns. The Au and Cu nanowires were electrochemically grown in polycarbonate etched ion-track membranes and transferred on infrared-transparent substrates. Significant antennalike plasmon resonances were observed in good agreement with exact light-scattering calculations. The resonances depend not only on length and diameter but also on the dielectric surrounding of the nanowire. The observed maximum extinction at resonance corresponds to an electromagnetic far-field enhancement by a factor of about 5.

SummaryThe combination of electrodeposition and polymeric templates created by heavy-ion irradiation followed by chemical track etching provides a large variety of poly- and single-crystalline nanowires of controlled size, geometry, composition, and surface morphology. Recent results obtained by our group on the fabrication, characterization and size-dependent properties of nanowires synthesized by this technique are reviewed, including investigations on electrical resistivity, surface plasmon resonances, and thermal instability.