Numerical simulation of multicomponent alloy solidification demands accuracy of thermophysical properties in order to obtain a numerical representation as close as possible to the physical reality. Some alloy properties are only seldom found in the literature. In this paper, a solution of Butler’s formulation for surface tension is presented for Al-Cu-Si ternary alloys, allowing the Gibbs-Thomson coefficient to be calculated as a function of Cu and Si contents. The importance of the Gibbs-Thomson coefficient is related to the reliability of predictions furnished by predictive microstructure growth models and of numerical computations of solidification thermal variables that will be strongly dependent on the values of the thermophysical properties adopted in the calculations. A numerical model based on Powell hybrid algorithm and a finite difference Jacobian approximation was coupled with a ThermoCalc TCAPI interface to assess the excess Gibbs energy of the liquid phase, permitting the surface tension and Gibbs-Thomson coefficient for Al-Cu-Si hypoeutectic alloys to be calculated. The computed results are presented as a function of the alloy composition.
Unlike the available mineral resources, the steelmaking processes have demanded raw material with lower phosphorus content to decrease the costs, energy use, and the residue generated within the steel plant. One alternative is to develop pretreatment of the iron ore concentrates producing raw materials with lower phosphorus. Depending on the mineral structure, a heat treatment combined with leaching could be an efficient way to achieve concentrates with low phosphorus (less than 0.01%), suitable for steelmaking processes. A fast and efficient way of applying energy to iron ore particles is the use of microwave to heat the particles. Thus, we propose a treatment using microwave heating while mixing with a dilute aqueous solution of sulfuric acid, followed by quenching during leaching with water, as a feasible route for the phosphorus removal from iron ore particles. We performed a design of experiment (DOE) to investigate the optimal conditions of heating and leaching, which maximize the rate of phosphorus removal. The structure of the iron ore particles after their treatment with microwave energy was observed by scanning electron microscopy (SEM). Thus, we analyze the optimal conditions for heating and leaching, the structure of the iron ore particles and which mechanism and rate equations are controlling the phosphorus removal. The results indicated that the average heating time is 10 min, the size of the crack of the order of 20µm and a leaching time of 8 min are adequate to achieve less than 0.01% of phosphorus. We demonstrated that under the most favorable combination of conditions for heating followed by leaching proposed in this study, the removal of the phosphorus content in the iron ore samples could reach 100%.
Welding is a widely used process that requires continuous developments to meet new application demands of mechanical projects under severe conditions. The homogeneity of metallurgical and mechanical properties in welded joints is the key factor for any welding process. The applications of external magnetic fields, mechanical vibration, and ultrasound are the fundamental steps to achieve success in improving these properties. The present work aimed at determining suitable processing conditions to achieve the desired balance between metallurgical and mechanical properties of 304L steel in TIG (Tungsten Inert Gas) welding under the application of an external magnetic field. The microstructural characteristics of the weld bead were analyzed by optical microscopy (OM) and scanning electron microscopy (SEM). In order to evaluate the mechanical properties of the welded specimen, its Vickers microhardness map and Charpy impact energy at −20 °C were obtained. In addition, corrosion tests were carried out in the saline medium to compare the corrosion resistance of the joint with that of the base metal and that without the magnetic field. It was found that the external magnetic field decreased the percentage of delta ferrite, improved the filling of the weld pool with the weld metal, and decreased the primary and secondary dendritic spacings. The Vickers microhardness value under the magnetic field was found to be lower than that without the magnetic field, and the Charpy test showed no significant variation in energy absorption. Moreover, the welded joint produced under the external magnetic field manifested less resistance to corrosion.
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