Calixarenes are considered as third generation supramolecules with hollow cavity-like architecture whereas nanoparticles are small entities with dimensions in the nanoscale. Many exciting achievements are seen when the calix system merges with nanoparticles which produces many fascinating facets in all fields of contemporary chemistry. The properties of nanoparticles which are tuned by calixarenes find applications in sensing, catalysis, molecular recognition, etc. Here, we have reviewed the chemistry of calix-based nanoparticles, and emphasis is laid on the modified, reducing, templated and stabilizing roles of calixarenes. This review covers the research being carried out in the domain of calix protected metal nanoparticles during last 18 years under the canopy of important 109 references. This article contains 58 figures which include 81 easy to understand structures. Calix-protected nanoparticles have enthralled researchers in the field of nanoscience with a tremendous growth in its applications, which heralds much promise to become in future a separate area of research.

A new fluorescence receptor calix[4]pyrrole-N-(quinoline-8-yl) acetamide (CAMQ) containing a pyrrolic ring connected via the meso-position was synthesized, purified and characterized by elemental analysis, NMR and mass spectroscopy. This compound was examined for its fluorescence properties towards different metal ions e.g. Ag(I), Hg(II), Co(II), Ca(II), Ni(II), Zn(II), Cr(II), Ba(II), Fe(II), Cu(II), Pb(II)and Mg(II) ions by spectrophotometry and spectrofluorometry. It was concluded that the compound (CAMQ) possessed significantly enhanced selectivity for Pb(II) and Cu(II) ions in dimethyl sulfoxide (DMSO) even at very low concentrations (1 μM). It exhibit 'turn-on' fluorescence when exposed to Pb(II) and Cu(II) and did so in preference to other metal ions. The binding constants, stoichiometry and quantum yields have been determined. The quenching mechanism was assessed using the Stern-Volmer equation and was also discussed.

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